Science > Physics > Bimetallic electrical Potential and conservation of charge
| Topic: |
Science > Physics |
| User: |
"Paul Stowe" |
| Date: |
05 Oct 2005 10:30:44 PM |
| Object: |
Bimetallic electrical Potential and conservation of charge |
As Volta demonstrated in the last decade of the 18th century when
two different metals are brought into physical contact (even when
both are, to all measurable detectability, electrically neutral,
a.k.a. no measurable potential) there will be generated a constant
and measurable non-zero Potential at the two opposing ends of the
bimetallic coupling. To my understanding, as long as no electrolyte
is present the metals are not be affected by any continuous circuit
created in this fashion. Now to my question,
Given that both metals are/were initially electrically neutral and
assuming conservation of charge, what creates and maintains the
measured Potential?
Paul Stowe
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| User: "Human Individual Metamorphosis" |
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| Title: Re: Bimetallic electrical Potential and conservation of charge |
05 Oct 2005 10:34:46 PM |
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"Paul Stowe" <TheAetherist@best.net> wrote in message
news:ng49k1lf7fecmsa8g239ehml2lb7f1necl@4ax.com...
As Volta demonstrated in the last decade of the 18th century when
two different metals are brought into physical contact (even when
both are, to all measurable detectability, electrically neutral,
a.k.a. no measurable potential) there will be generated a constant
and measurable non-zero Potential at the two opposing ends of the
bimetallic coupling. To my understanding, as long as no electrolyte
is present the metals are not be affected by any continuous circuit
created in this fashion. Now to my question,
Given that both metals are/were initially electrically neutral and
assuming conservation of charge, what creates and maintains the
measured Potential?
Paul Stowe
It is potential, not current or power.
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| User: "" |
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| Title: Re: Bimetallic electrical Potential and conservation of charge |
05 Oct 2005 10:54:23 PM |
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In sci.physics Human Individual Metamorphosis <nospam@nospam.com> wrote:
"Paul Stowe" <TheAetherist@best.net> wrote in message
news:ng49k1lf7fecmsa8g239ehml2lb7f1necl@4ax.com...
As Volta demonstrated in the last decade of the 18th century when
two different metals are brought into physical contact (even when
both are, to all measurable detectability, electrically neutral,
a.k.a. no measurable potential) there will be generated a constant
and measurable non-zero Potential at the two opposing ends of the
bimetallic coupling. To my understanding, as long as no electrolyte
is present the metals are not be affected by any continuous circuit
created in this fashion. Now to my question,
Given that both metals are/were initially electrically neutral and
assuming conservation of charge, what creates and maintains the
measured Potential?
Paul Stowe
It is potential, not current or power.
Yep, that's the question.
Anyway, to grossly oversimplfy, it is because of where the electrons
are; add heat to enhance the effect.
--
Jim Pennino
Remove .spam.sux to reply.
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| User: "Paul Stowe" |
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| Title: Re: Bimetallic electrical Potential and conservation of charge |
06 Oct 2005 07:49:14 PM |
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On Thu, 6 Oct 2005 03:54:23 +0000 (UTC), wrote:
In sci.physics Human Individual Metamorphosis <nospam@nospam.com> wrote:
"Paul Stowe" <TheAetherist@best.net> wrote in message
news:ng49k1lf7fecmsa8g239ehml2lb7f1necl@4ax.com...
As Volta demonstrated in the last decade of the 18th century when
two different metals are brought into physical contact (even when
both are, to all measurable detectability, electrically neutral,
a.k.a. no measurable potential) there will be generated a constant
and measurable non-zero Potential at the two opposing ends of the
bimetallic coupling. To my understanding, as long as no electrolyte
is present the metals are not be affected by any continuous circuit
created in this fashion. Now to my question,
Given that both metals are/were initially electrically neutral and
assuming conservation of charge, what creates and maintains the
measured Potential?
Paul Stowe
It is potential, not current or power.
Unless one can violate Ohm's Law V = IR, I = V/R. Thus for any finite
positive value for V & R, I is finite positive. Thus P = IV so there
will exist available (P)ower as long a Potential V is non zero.
Yep, that's the question.
Indeed, which is why I asked it :)
Anyway, to grossly oversimplfy, it is because of where the electrons
are; add heat to enhance the effect.
While I agree your response is way to vague. What do you mean by
"it is because of where the electrons are"
Aren't the alot of free conduction electrons in metals? As in,
http://www.britannica.com/eb/article-9035281
Paul Stowe
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| User: "Bilge" |
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| Title: Re: Bimetallic electrical Potential and conservation of charge |
08 Oct 2005 10:57:00 AM |
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Paul Stowe:
Unless one can violate Ohm's Law V = IR, I = V/R.
I can violate ohm's law in quite a few way, several of which are:
(1) an ordinary vacuum tube, (follows the child-langmuir law),
(2) any ordinary diode, (follows the diode equation)
(3) any ordinary transistor (ibid)
(4) any ordinary FET, MOSFET or other field effect device, (ibid)
(5) a spark plug
Which I think covers just about every electronic device in
existence except for wires, which are called resistors when
they don't conduct very well. Taken as a whole, one would have
to suspect that ohm's law is fairly specific to particular
class of phenomena, the explanation of which is not found in
ohm's law.
Thus for any finite positive value for V & R, I is finite positive.
Thus P = IV so there will exist available (P)ower as long a Potential
V is non zero.
There will? Then how come the potential that binds electrons to the
surface of a conductor doesn't result in the conductor radiatiating
until the conduction electrons fall off?
The `V' in V = IR is not an electrosatic potential. It's the
``emf'' also called the electromotance. It's a force per unit
charge, which has no explanation within classical E&M without
the ad hoc assumption that J = \sigma E in a conductor, without
any explanation of what makes a conductor a conductor or why
that should be the case.
Obviously, that conflicts with the lorenz force, which says that
charges are accelerated in electric fields, not that charges move at
constant velocities proportional to the electric fields. Ohm made such
an ad hoc assumption based on the time honored tradition of deriving an
equation from the curve fit to empirical data and making it useful by
realizing that he only needed the linear term to have a good rule of
thumb that would likely be explained later by a more comprehensive
theory. The arrival of quantum mechanics fulfilled that expectation,
but that means the explanation of conductors requires quantum mechanics.
Classical E&M doesn't cut it.
Aren't the alot of free conduction electrons in metals?
Sure. It's called the free electron model. The next order of
improvement is called the nearly free electron model of conductors.
As in,
http://www.britannica.com/eb/article-9035281
As in, ``Introduction to Solid State Physics,'', Kittel, C.
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| User: "Rod Ryker" |
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| Title: Re: Bimetallic electrical Potential and conservation of charge |
08 Oct 2005 07:21:52 PM |
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"Bilge" <dubious@radioactivex.lebesque-al.net>
wrote in message
news:slrndkfua6.q37.dubious@radioactivex.lebesque-al.net...
Paul Stowe:
Unless one can violate Ohm's Law V = IR, I =
V/R.
I can violate ohm's law in quite a few way,
several of which are:
(1) an ordinary vacuum tube, (follows the
child-langmuir law),
(2) any ordinary diode, (follows the diode
equation)
(3) any ordinary transistor (ibid)
(4) any ordinary FET, MOSFET or other field
effect device, (ibid)
(5) a spark plug
Rod: You forgot welding arc's, and you would still
be wrong.
Which I think covers just about every
electronic device in
existence except for wires, which are called
resistors when
they don't conduct very well. Taken as a whole,
one would have
to suspect that ohm's law is fairly specific to
particular
class of phenomena, the explanation of which is
not found in
ohm's law.
Rod: And you are wrong.
Thus for any finite positive value for V & R,
I is finite positive.
Thus P = IV so there will exist available
(P)ower as long a Potential
V is non zero.
There will? Then how come the potential that
binds electrons to the
surface of a conductor doesn't result in the
conductor radiatiating
until the conduction electrons fall off?
The `V' in V = IR is not an electrosatic
potential. It's the
``emf'' also called the electromotance. It's a
force per unit
charge, which has no explanation within
classical E&M without
the ad hoc assumption that J = \sigma E in a
conductor, without
any explanation of what makes a conductor a
conductor or why
that should be the case.
Obviously, that conflicts with the lorenz
force, which says that
charges are accelerated in electric fields, not
that charges move at
constant velocities proportional to the electric
fields. Ohm made such
an ad hoc assumption based on the time honored
tradition of deriving an
equation from the curve fit to empirical data
and making it useful by
realizing that he only needed the linear term to
have a good rule of
thumb that would likely be explained later by a
more comprehensive
theory. The arrival of quantum mechanics
fulfilled that expectation,
but that means the explanation of conductors
requires quantum mechanics.
Classical E&M doesn't cut it.
Aren't the alot of free conduction electrons
in metals?
Sure. It's called the free electron model. The
next order of
improvement is called the nearly free electron
model of conductors.
As in,
http://www.britannica.com/eb/article-9035281
As in, ``Introduction to Solid State
Physics,'', Kittel, C.
Rod: You provided a very poor post Bilge. :(
--
Rod Ryker...
The intricacies of nature is man's cannon fodder.
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| User: "Bilge" |
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| Title: Re: Bimetallic electrical Potential and conservation of charge |
12 Oct 2005 01:18:32 PM |
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Rod Ryker:
Rod: You forgot welding arc's, and you would still
be wrong.
Stop breathing your acetylene. Even if it's too late for
what's left of your brain to recover, you'll still save a
lot of money in welding supplies.
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| User: "Tom Roberts" |
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| Title: Re: Bimetallic electrical Potential and conservation of charge |
06 Oct 2005 08:52:24 PM |
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As nobody else has answered, let me. Uncle Al tried, but used so much
jargon his answer is impenetrable.
Paul Stowe wrote:
As Volta demonstrated in the last decade of the 18th century when
two different metals are brought into physical contact (even when
both are, to all measurable detectability, electrically neutral,
a.k.a. no measurable potential) there will be generated a constant
and measurable non-zero Potential at the two opposing ends of the
bimetallic coupling. To my understanding, as long as no electrolyte
is present the metals are not be affected by any continuous circuit
created in this fashion. Now to my question,
Given that both metals are/were initially electrically neutral and
assuming conservation of charge, what creates and maintains the
measured Potential?
Here's a high-level and rather loose explanation:
Metals are composed of atoms that bond together such that some of the
electrons are tightly bound to the nuclei, and others (conduction
electrons) are essentially free to move around the metal (but normally
remain inside the metal). Different metals have different ratios of
these types of electrons, and blocks of different metals have different
densities of nuclei plus bound electrons. Place two different blocks of
metal together and at the joined surface the two blocks' nuclei plus
bound electrons will set up a nonuniform electric field near the
junction (due to the difference in their densities) and the conduction
electrons in both blocks will quickly move to cancel it; in doing so one
block's electrons move further than the other's. This results in a
difference in the density of conduction electrons on the other sides of
the blocks, which when added to the constant density of nuclei plus
bound electrons sets up an electric field there, which yields a
potential difference between the outer sides (the nuclei plus bound
electrons have constant density throughout the metal, but the conduction
electrons don't).
Note that when you connect to the outer sides of the blocks you must
beware of the same effect at the connections.
This is a loose description -- do not rely on it for details; I have
neglected the atomic structure, which is important. Remember that
"placing blocks together" means their electrons repel each other and
prevent them from interpenetrating each other; the conduction electrons
by themselves cannot do that (they move freely, even across the boundary
if necessary), but the nuclei plus bound electrons can.
Tom Roberts tjroberts@lucent.com
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| User: "Paul Stowe" |
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| Title: Re: Bimetallic electrical Potential and conservation of charge |
08 Oct 2005 11:51:47 AM |
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On Fri, 07 Oct 2005 01:52:24 GMT, Tom Roberts <tjroberts@lucent.com> wrote:
As nobody else has answered, let me. Uncle Al tried, but used so much
jargon his answer is impenetrable.
Paul Stowe wrote:
As Volta demonstrated in the last decade of the 18th century when
two different metals are brought into physical contact (even when
both are, to all measurable detectability, electrically neutral,
a.k.a. no measurable potential) there will be generated a constant
and measurable non-zero Potential at the two opposing ends of the
bimetallic coupling. To my understanding, as long as no electrolyte
is present the metals are not be affected by any continuous circuit
created in this fashion. Now to my question,
Given that both metals are/were initially electrically neutral and
assuming conservation of charge, what creates and maintains the
measured Potential?
Here's a high-level and rather loose explanation:
Good enough for now...
Metals are composed of atoms that bond together such that some of
the electrons are tightly bound to the nuclei, and others (conduction
electrons) are essentially free to move around the metal (but normally
remain inside the metal). Different metals have different ratios of
these types of electrons, and blocks of different metals have different
densities of nuclei plus bound electrons. Place two different blocks of
metal together and at the joined surface the two blocks' nuclei plus
bound electrons will set up a nonuniform electric field near the
junction (due to the difference in their densities) and the conduction
electrons in both blocks will quickly move to cancel it; in doing so one
block's electrons move further than the other's. This results in a
difference in the density of conduction electrons on the other sides of
the blocks, which when added to the constant density of nuclei plus
bound electrons sets up an electric field there, which yields a
potential difference between the outer sides (the nuclei plus bound
electrons have constant density throughout the metal, but the conduction
electrons don't).
So, is it correct to say that in this situation there exists no
electrically neutral state?
Note that when you connect to the outer sides of the blocks you must
beware of the same effect at the connections.
Of course. Usually these are considered 'point' (very little
surface) contacts.
This is a loose description -- do not rely on it for details; I
have neglected the atomic structure, which is important. Remember
that "placing blocks together" means their electrons repel each
other and prevent them from interpenetrating each other; the
conduction electrons by themselves cannot do that (they move freely,
even across the boundary if necessary), but the nuclei plus bound
electrons can.
cannot?
Paul Stowe
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| User: "Tom Roberts" |
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| Title: Re: Bimetallic electrical Potential and conservation of charge |
08 Oct 2005 07:02:20 PM |
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Paul Stowe wrote:
On Fri, 07 Oct 2005 01:52:24 GMT, Tom Roberts <tjroberts@lucent.com> wrote:
Metals are composed of atoms that bond together such that some of
the electrons are tightly bound to the nuclei, and others (conduction
electrons) are essentially free to move around the metal (but normally
remain inside the metal). Different metals have different ratios of
these types of electrons, and blocks of different metals have different
densities of nuclei plus bound electrons. Place two different blocks of
metal together and at the joined surface the two blocks' nuclei plus
bound electrons will set up a nonuniform electric field near the
junction (due to the difference in their densities) and the conduction
electrons in both blocks will quickly move to cancel it; in doing so one
block's electrons move further than the other's. This results in a
difference in the density of conduction electrons on the other sides of
the blocks, which when added to the constant density of nuclei plus
bound electrons sets up an electric field there, which yields a
potential difference between the outer sides (the nuclei plus bound
electrons have constant density throughout the metal, but the conduction
electrons don't).
So, is it correct to say that in this situation there exists no
electrically neutral state?
No. As I discussed above, an electrically-neutral conducting block can
become electrically polarized, while remaining neutral.
IOW: "electrically neutral" discusses the electric monopole, while
electric polarization is the dipole; they are independent.
Tom Roberts tjroberts@lucent.com
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| User: "Rod Ryker" |
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| Title: Re: Bimetallic electrical Potential and conservation of charge |
08 Oct 2005 08:31:53 PM |
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"Tom Roberts" <> wrote in
message
news:g6Z1f.1153$Rh5.1007@newssvr19.news.prodigy.com...
Paul Stowe wrote:
On Fri, 07 Oct 2005 01:52:24 GMT, Tom Roberts
<> wrote:
Metals are composed of atoms that bond
together such that some of
the electrons are tightly bound to the nuclei,
and others (conduction
electrons) are essentially free to move around
the metal (but normally
remain inside the metal). Different metals
have different ratios of
these types of electrons, and blocks of
different metals have different
densities of nuclei plus bound electrons.
Place two different blocks of
metal together and at the joined surface the
two blocks' nuclei plus
bound electrons will set up a nonuniform
electric field near the
junction (due to the difference in their
densities) and the conduction
electrons in both blocks will quickly move to
cancel it; in doing so one
block's electrons move further than the
other's. This results in a
difference in the density of conduction
electrons on the other sides of
the blocks, which when added to the constant
density of nuclei plus
bound electrons sets up an electric field
there, which yields a
potential difference between the outer sides
(the nuclei plus bound
electrons have constant density throughout the
metal, but the conduction
electrons don't).
So, is it correct to say that in this
situation there exists no
electrically neutral state?
No. As I discussed above, an
electrically-neutral conducting block can
become electrically polarized, while remaining
neutral.
IOW: "electrically neutral" discusses the
electric monopole, while
electric polarization is the dipole; they are
independent.
Tom Roberts
Rod: Then it seems electrons are kind of Dipoles,
yes?
--
Rod Ryker...
The intricacies of nature is man's cannon fodder.
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| User: "Tom Roberts" |
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| Title: Re: Bimetallic electrical Potential and conservation of charge |
08 Oct 2005 09:08:18 PM |
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Rod Ryker wrote:
"Tom Roberts" <tjroberts@lucent.com> wrote in
message
news:g6Z1f.1153$Rh5.1007@newssvr19.news.prodigy.com...
IOW: "electrically neutral" discusses the electric monopole, while
electric polarization is the dipole; they are independent.
Rod: Then it seems electrons are kind of Dipoles,
yes?
No. Electrons are electric monopoles. Their electric dipole moment is
measured to be consistent with zero (as are all higher moments that have
been measured).
They do, however, have a nonzero magnetic dipole moment (which is, of
course, completely different).
The metal blocks I was discussing are electrically neutral but have
nonzero electric dipoles when placed together (as discussed).
Tom Roberts tjroberts@lucent.com
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| User: "Rod Ryker" |
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| Title: Re: Bimetallic electrical Potential and conservation of charge |
08 Oct 2005 11:20:57 PM |
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"Tom Roberts" <> wrote in
message
news:mY_1f.1655$Si4.1639@newssvr30.news.prodigy.com...
Rod Ryker wrote:
"Tom Roberts" < > wrote in
message
news:g6Z1f.1153$Rh5.1007@newssvr19.news.prodigy.com...
IOW: "electrically neutral" discusses the
electric monopole, while
electric polarization is the dipole; they are
independent.
Rod: Then it seems electrons are kind of
Dipoles,
yes?
No. Electrons are electric monopoles. Their
electric dipole moment is
measured to be consistent with zero (as are all
higher moments that have
been measured).
They do, however, have a nonzero magnetic dipole
moment (which is, of
course, completely different).
Rod: You are saying a rubber balloon holding many
electrons,
after rubbed agaisnt ones hair, are attracted and
NO dipole attraction? ;)
How can these electrons on the balloon be sooooo
tightly packed
without repelling each other?
The metal blocks I was discussing are
electrically neutral but have
nonzero electric dipoles when placed together
(as discussed).
Tom Roberts
--
Rod Ryker...
The intricacies of nature is man's cannon fodder.
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| User: "Paul Stowe" |
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| Title: Re: Bimetallic electrical Potential and conservation of charge |
09 Oct 2005 04:44:55 PM |
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On Sun, 09 Oct 2005 00:02:20 GMT, Tom Roberts <tjroberts@lucent.com> wrote:
Paul Stowe wrote:
On Fri, 07 Oct 2005 01:52:24 GMT, Tom Roberts <tjroberts@lucent.com> wrote:
Metals are composed of atoms that bond together such that some of
the electrons are tightly bound to the nuclei, and others (conduction
electrons) are essentially free to move around the metal (but normally
remain inside the metal). Different metals have different ratios of
these types of electrons, and blocks of different metals have different
densities of nuclei plus bound electrons. Place two different blocks of
metal together and at the joined surface the two blocks' nuclei plus
bound electrons will set up a nonuniform electric field near the
junction (due to the difference in their densities) and the conduction
electrons in both blocks will quickly move to cancel it; in doing so one
block's electrons move further than the other's. This results in a
difference in the density of conduction electrons on the other sides of
the blocks, which when added to the constant density of nuclei plus
bound electrons sets up an electric field there, which yields a
potential difference between the outer sides (the nuclei plus bound
electrons have constant density throughout the metal, but the conduction
electrons don't).
So, is it correct to say that in this situation there exists no
electrically neutral state?
No. As I discussed above, an electrically-neutral conducting block can
become electrically polarized, while remaining neutral.
If the system becomes constantly polarized just from plane
contact of their surfaces, when both, in isolation, were
initially totally neutral and without any dipole such that
when conbined there is sustainable constant power draw in
the circuit (IV) in the case of closing a loop circuit
there must be a source for this energy. It has to come from
somewhere to constantly pump an electrical current around
against resistance. If the two metals are electrically
neutral, and remain, so where does the force to produces this
energy come from, thermal? Any other guesses?
IOW: "electrically neutral" discusses the electric monopole,
while electric polarization is the dipole; they are independent.
To sustain a macroscopic dipole and to be able to draw energy
form the circuit a net force needs to be created. You can't
get something from nothing, right?
Paul Stowe
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| User: "Tom Roberts" |
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| Title: Re: Bimetallic electrical Potential and conservation of charge |
09 Oct 2005 05:39:17 PM |
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Paul Stowe wrote:
On Sun, 09 Oct 2005 00:02:20 GMT, Tom Roberts <tjroberts@lucent.com> wrote:
On Fri, 07 Oct 2005 01:52:24 GMT, Tom Roberts <tjroberts@lucent.com> wrote:
Metals are composed of atoms [...]
So, is it correct to say that in this situation there exists no
electrically neutral state?
No. As I discussed above, an electrically-neutral conducting block can
become electrically polarized, while remaining neutral.
If the system becomes constantly polarized just from plane
contact of their surfaces, when both, in isolation, were
initially totally neutral and without any dipole such that
when conbined there is sustainable constant power draw in
the circuit (IV) in the case of closing a loop circuit
there must be a source for this energy.
Except, as I pointed out before, you must consider this very same effect
when you connect a wire from one outer side to the other (your "in the
case of closing a loop circuit"). In fact, the conduction electrons will
"just happen" to arrange themselves so no current flows (except perhaps
briefly when initially connected).
Yes, there can remain a permanent electric dipole between the outer
faces; there is also one in the wire, and they are equal.
To sustain a macroscopic dipole and to be able to draw energy
form the circuit a net force needs to be created. You can't
get something from nothing, right?
Except for transients when connected, there is no current, no "net
force", no "energy draw", and no "something from nothing". Everything
just sits there. <shrug>
Exercise for the reader: assume there are transients when the
wire is connected between the two outer faces. Where does the
energy for them come from (qualitatively)? Be sure to include
EM radiation. Hint: Compare to what happens when disconnected.
Tom Roberts tjroberts@lucent.com
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| User: "N:dlzc D:aol T:com \dlzc\ N: dlzc1 D:cox" |
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| Title: Re: Bimetallic electrical Potential and conservation of charge |
05 Oct 2005 11:36:35 PM |
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Dear Paul Stowe:
"Paul Stowe" <TheAetherist@best.net> wrote in message
news:ng49k1lf7fecmsa8g239ehml2lb7f1necl@4ax.com...
As Volta demonstrated in the last decade of the 18th century
when two different metals are brought into physical contact
(even when both are, to all measurable detectability,
electrically neutral, a.k.a. no measurable potential) there
will
be generated a constant and measurable non-zero Potential
at the two opposing ends of the bimetallic coupling. To my
understanding, as long as no electrolyte is present the metals
are not be affected by any continuous circuit created in this
fashion.
"thermocouple", "thermopile", "Fermi energy"
Now to my question,
Given that both metals are/were initially electrically neutral
and
assuming conservation of charge, what creates and maintains
the
measured Potential?
http://www.nphheaters.com/technical/thermo_letter.htm
David A. Smith
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| User: "Rod Ryker" |
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| Title: Re: Bimetallic electrical Potential and conservation of charge |
06 Oct 2005 12:59:14 AM |
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N:dlzc D:aol T:com (dlzc) <N: dlzc1 D:cox T:net@nospam.com> wrote in message
news:iR11f.13260$lq6.3837@fed1read01...
Dear Paul Stowe:
"Paul Stowe" <TheAetherist@best.net> wrote in message
news:ng49k1lf7fecmsa8g239ehml2lb7f1necl@4ax.com...
As Volta demonstrated in the last decade of the 18th century
when two different metals are brought into physical contact
(even when both are, to all measurable detectability,
electrically neutral, a.k.a. no measurable potential) there
will
be generated a constant and measurable non-zero Potential
at the two opposing ends of the bimetallic coupling. To my
understanding, as long as no electrolyte is present the metals
are not be affected by any continuous circuit created in this
fashion.
"thermocouple", "thermopile", "Fermi energy"
Now to my question,
Given that both metals are/were initially electrically neutral
and
assuming conservation of charge, what creates and maintains
the
measured Potential?
http://www.nphheaters.com/technical/thermo_letter.htm
David A. Smith
Rod: After reviewing the first illustration and text of
the site you posted, I see that a short circuit is illustrated. :)
--
Rod Ryker...
The intricacies of nature is man's cannon fodder.
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| User: "N:dlzc D:aol T:com \dlzc\ N: dlzc1 D:cox" |
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| Title: Re: Bimetallic electrical Potential and conservation of charge |
06 Oct 2005 08:15:49 AM |
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Dear Rod Ryker:
"Rod Ryker" <rryker@fuse.net> wrote in message
news:72681$4344bd2b$d8442ec5$19500@FUSE.NET...
N:dlzc D:aol T:com (dlzc) <N: dlzc1 D:cox T:net@nospam.com>
wrote in message
news:iR11f.13260$lq6.3837@fed1read01...
Dear Paul Stowe:
"Paul Stowe" <TheAetherist@best.net> wrote in message
news:ng49k1lf7fecmsa8g239ehml2lb7f1necl@4ax.com...
As Volta demonstrated in the last decade of the 18th century
when two different metals are brought into physical contact
(even when both are, to all measurable detectability,
electrically neutral, a.k.a. no measurable potential) there
will
be generated a constant and measurable non-zero Potential
at the two opposing ends of the bimetallic coupling. To my
understanding, as long as no electrolyte is present the
metals
are not be affected by any continuous circuit created in
this
fashion.
"thermocouple", "thermopile", "Fermi energy"
Now to my question,
Given that both metals are/were initially electrically
neutral and assuming conservation of charge, what
creates and maintains the measured Potential?
http://www.nphheaters.com/technical/thermo_letter.htm
Rod: After reviewing the first illustration and text of
the site you posted, I see that a short circuit is illustrated.
:)
Yes. A wheatstone bridge could be used to "un short circuit" it,
by stopping any current flow. I suppose the potential could
drive a FET directly...
But Paul seemed more interested in where the potential that can
*drive* the short circuit comes from, rather than applications.
It comes from the "conduction electron behavior" of the
metals/alloys/composites forming the two joined elements.
David A. Smith
.
|
|
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| User: "Paul Stowe" |
|
| Title: Re: Bimetallic electrical Potential and conservation of charge |
06 Oct 2005 07:38:48 PM |
|
|
On Thu, 6 Oct 2005 06:15:49 -0700, "N:dlzc D:aol T:com \(dlzc\)" <N: dlzc1 D:cox
T:net@nospam.com> wrote:
Dear Rod Ryker:
"Rod Ryker" <rryker@fuse.net> wrote in message
news:72681$4344bd2b$d8442ec5$19500@FUSE.NET...
N:dlzc D:aol T:com (dlzc) <N: dlzc1 D:cox T:net@nospam.com>
wrote in message
news:iR11f.13260$lq6.3837@fed1read01...
Dear Paul Stowe:
"Paul Stowe" <TheAetherist@best.net> wrote in message
news:ng49k1lf7fecmsa8g239ehml2lb7f1necl@4ax.com...
As Volta demonstrated in the last decade of the 18th century
when two different metals are brought into physical contact
(even when both are, to all measurable detectability,
electrically neutral, a.k.a. no measurable potential) there
will be generated a constant and measurable non-zero Potential
at the two opposing ends of the bimetallic coupling. To my
understanding, as long as no electrolyte is present the
metals are not be affected by any continuous circuit created
in this fashion.
"thermocouple", "thermopile", "Fermi energy"
I guess I don't understand this without a thermal gradient.
With a thermal gradient the Seebeck Effect, sure.
Now to my question,
Given that both metals are/were initially electrically
neutral and assuming conservation of charge, what
creates and maintains the measured Potential?
http://www.nphheaters.com/technical/thermo_letter.htm
Rod: After reviewing the first illustration and text of
the site you posted, I see that a short circuit is illustrated.
:)
Yes. A wheatstone bridge could be used to "un short circuit"
it, by stopping any current flow. I suppose the potential
could drive a FET directly...
But Paul seemed more interested in where the potential that can
*drive* the short circuit comes from, rather than applications.
Right. As Volta realized the Potential (thus available power)
is interesting but too small to be useful. Thus he introduced
the electrolyte and thus was born the modern version of the
common battery.
It comes from the "conduction electron behavior" of the
metals/alloys/composites forming the two joined elements.
I'm sure it is due to a discontinuity at the connecting plane of
the two metals. But, as Al points out in his reply, even
dielectrics have this effect. That's why a clear plastic cover
on a paper report sticks & crackles when separated after being
left sittingstill & unattended for awhile.
With metals one would think that the free conduction electrons
would quickly & easily rearrange to counter any such
discontinuous Potentials. One would not expect a continuous
Potential (thus slight available power) from such a static system.
But, more importantly, if charge is conserved, how can this happen?
Paul Stowe
David A. Smith
.
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| User: "sal" |
|
| Title: Re: Bimetallic electrical Potential and conservation of charge |
07 Oct 2005 03:29:41 PM |
|
|
On Fri, 07 Oct 2005 00:38:48 +0000, Paul Stowe wrote:
[ snip ]
I'm sure it is due to a discontinuity at the connecting plane of
the two metals. But, as Al points out in his reply, even
dielectrics have this effect. That's why a clear plastic cover on
a paper report sticks & crackles when separated after being left
sittingstill & unattended for awhile.
I don't pretend to understand thermocouples, but I think I understand
what's going on with a clear plastic sheet and it's a little
different. You're starting with a sheet of plastic which _already_
has a charge on it, donated by whatever black-box process; static
charges are easy to come by and some clear covers seem to come from
the factory pre-charged. Since the plastic is a non-conductor, once
it's charged it tends to stay that way.
And, once you get a charge on a non-conducting sheet, if you place it
in contact with something else -- preferably a conductor of some sort
-- you make a capacitor. It's a capacitor where the charges are
"frozen in place" on one plate, but none the less it acts a lot like a
regular capacitor in most ways.
Let the permanently charged sheet of plastic sit on <whatever> for a
while, and it will induce a charge in the sheet of <whatever>. If the
plastic is negative, then some of the electrons in the other sheet
will tend to run off into the environment by whatever paths you
provide for them, leaving a positive charge behind.
The "capacitor", at full charge, might be at a volt or two, or perhaps
much less.
Now, pull the plastic sheet off whatever it's on. As you separate the
plates of the "capacitor" you boost the voltage to which it's charged,
as a quick glance at the formula for the capacity of a simple
parallel-plate capacitor will show. The "work" you put in while
pulling the plastic away is what provides the energy for the crackling
you hear.
Here's an amusing experiment that sort of "institutionalizes" the
effect. Stick a thick clear plastic sheet to a solid backing, with a
handle on it. A sheet of cardboard for backing and an empty paper
towel roll for a handle will do. Get the plastic charged, one way or
another (rub with fur or something). (Maybe you should do that first,
before sticking it to the backing, come to think of it. Several
stacked sheets of plastic might be good here, too. Experiment...)
Next, find yourself an aluminum pie pan, and set it down on some nice
non-conducting surface (a plastic tablecloth will probably do, but you
want to make sure there's nothing conductive underneath it, either).
Stick it firmly in place somehow, so it won't just "lift up" when
pulled gently; but make sure it's not grounded.
NOW, the fun bit. Put your plastic "plate" down on the pie pan, with
as much of it in contact as you can get. Touch the pie pan to ground
it, so the capacitor can "charge" (you might get a tiny shock here,
but you probably won't feel anything).
FINALLY, lift the plastic "plate" by its handle. When it's a few feet
from the pie plate, touch the pie plate. ZZAAAP!
You can do it again, too (just remember to ground the pie pan
momentarily while the plastic sheet is in contact with it each time).
It'll work for as many cycles as you like, because the energy's coming
from the work you do pulling the plastic sheet off the pie pan, and
the charges on the plastic sheet aren't getting "used up".
If you try it let me know if it works. I've read about it but never
got around to actually making one! (And I don't recall the name --
it's a somebody-or-other generator, I think, but I forget who
"somebody" is.)
--
Nospam becomes physicsinsights to fix the email
.
|
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| User: "N:dlzc D:aol T:com \dlzc\ N: dlzc1 D:cox" |
|
| Title: Re: Bimetallic electrical Potential and conservation of charge |
07 Oct 2005 06:08:41 PM |
|
|
Dear sal:
"sal" <pragmatist@nospam.org> wrote in message
news:pan.2005.10.07.20.29.38.805456@nospam.org...
On Fri, 07 Oct 2005 00:38:48 +0000, Paul Stowe wrote:
....
If you try it let me know if it works. I've read about it but
never
got around to actually making one! (And I don't recall the
name --
it's a somebody-or-other generator, I think, but I forget who
"somebody" is.)
Another neat rick is to adhere clear "scotch tape" on a mirror.
Take the mirror into a *very* dark room, then *RIP* the tape off.
Should be some glow created at the point of separation, since
"adhesives stick to electrons"... ;>)
David A. Smith
.
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| User: "Rod Ryker" |
|
| Title: Re: Bimetallic electrical Potential and conservation of charge |
07 Oct 2005 01:14:30 AM |
|
|
Paul Stowe <TheAetherist@best.net> wrote in message
news:i5fbk1dd2ajkppk5mlgdmq8v7orgb58tsg@4ax.com...
On Thu, 6 Oct 2005 06:15:49 -0700, "N:dlzc D:aol T:com \(dlzc\)" <N: dlzc1
D:cox
T:net@nospam.com> wrote:
Dear Rod Ryker:
"Rod Ryker" <rryker@fuse.net> wrote in message
news:72681$4344bd2b$d8442ec5$19500@FUSE.NET...
N:dlzc D:aol T:com (dlzc) <N: dlzc1 D:cox T:net@nospam.com>
wrote in message
news:iR11f.13260$lq6.3837@fed1read01...
Dear Paul Stowe:
"Paul Stowe" <TheAetherist@best.net> wrote in message
news:ng49k1lf7fecmsa8g239ehml2lb7f1necl@4ax.com...
As Volta demonstrated in the last decade of the 18th century
when two different metals are brought into physical contact
(even when both are, to all measurable detectability,
electrically neutral, a.k.a. no measurable potential) there
will be generated a constant and measurable non-zero Potential
at the two opposing ends of the bimetallic coupling. To my
understanding, as long as no electrolyte is present the
metals are not be affected by any continuous circuit created
in this fashion.
"thermocouple", "thermopile", "Fermi energy"
I guess I don't understand this without a thermal gradient.
With a thermal gradient the Seebeck Effect, sure.
Now to my question,
Given that both metals are/were initially electrically
neutral and assuming conservation of charge, what
creates and maintains the measured Potential?
http://www.nphheaters.com/technical/thermo_letter.htm
Rod: After reviewing the first illustration and text of
the site you posted, I see that a short circuit is illustrated.
:)
Yes. A wheatstone bridge could be used to "un short circuit"
it, by stopping any current flow. I suppose the potential
could drive a FET directly...
But Paul seemed more interested in where the potential that can
*drive* the short circuit comes from, rather than applications.
Right. As Volta realized the Potential (thus available power)
is interesting but too small to be useful. Thus he introduced
the electrolyte and thus was born the modern version of the
common battery.
It comes from the "conduction electron behavior" of the
metals/alloys/composites forming the two joined elements.
David A. Smith
I'm sure it is due to a discontinuity at the connecting plane of
the two metals. But, as Al points out in his reply, even
dielectrics have this effect. That's why a clear plastic cover
on a paper report sticks & crackles when separated after being
left sittingstill & unattended for awhile.
With metals one would think that the free conduction electrons
would quickly & easily rearrange to counter any such
discontinuous Potentials. One would not expect a continuous
Potential (thus slight available power) from such a static system.
But, more importantly, if charge is conserved, how can this happen?
Paul Stowe
Rod: Regardless of how joined, or later when heat is applied,
the metals are under pressure.
The earth's magnetic field is the applicable reason that a current flows,
and a voltage is measured.
--
Rod Ryker...
The intricacies of nature is man's cannon fodder.
.
|
|
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| User: "N:dlzc D:aol T:com \dlzc\ N: dlzc1 D:cox" |
|
| Title: Re: Bimetallic electrical Potential and conservation of charge |
07 Oct 2005 07:58:33 AM |
|
|
Dear Rod Ryker:
"Rod Ryker" <rryker@fuse.net> wrote in message
news:8570b$4346170c$d8442838$25078@FUSE.NET...
....
Rod: Regardless of how joined, or later when heat is applied,
the metals are under pressure.
The earth's magnetic field is the applicable reason that a
current flows, and a voltage is measured.
So the effect disappears inside Helmholz coils? I don't think
so.
I believe from what Tom said, the effect is originated at the
interface. You might think of it as "entropy pressure" trying to
merge the two dissimilar metals, which is quite likely not
right...
David A. Smith
.
|
|
|
| User: "Rod Ryker" |
|
| Title: Re: Bimetallic electrical Potential and conservation of charge |
07 Oct 2005 01:47:52 PM |
|
|
N:dlzc D:aol T:com (dlzc) <N: dlzc1 D:cox T:net@nospam.com> wrote in message
news:Rhu1f.32218$lq6.15698@fed1read01...
Dear Rod Ryker:
"Rod Ryker" <rryker@fuse.net> wrote in message
news:8570b$4346170c$d8442838$25078@FUSE.NET...
...
Rod: Regardless of how joined, or later when heat is applied,
the metals are under pressure.
The earth's magnetic field is the applicable reason that a
current flows, and a voltage is measured.
So the effect disappears inside Helmholz coils? I don't think
so.
Rod: If you have a web site confirming an identical experiment
then please share. :)
Although the earth's magnetic field is in effect null
in this scenario, uniform or not, the magnetic pressure from the
Helmholtz coil pair raises the temperature of the metals.
I believe from what Tom said, the effect is originated at the
interface. You might think of it as "entropy pressure" trying to
merge the two dissimilar metals, which is quite likely not
right...
Rod: Agreed.
--
Rod Ryker...
The intricacies of nature is man's cannon fodder.
David A. Smith
.
|
|
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| User: "N:dlzc D:aol T:com \dlzc\ N: dlzc1 D:cox" |
|
| Title: Re: Bimetallic electrical Potential and conservation of charge |
07 Oct 2005 03:24:53 PM |
|
|
Dear Rod Ryker:
"Rod Ryker" <rryker@fuse.net> wrote in message
news:d4348$4346c2d2$d8442aed$6932@FUSE.NET...
N:dlzc D:aol T:com (dlzc) <N: dlzc1 D:cox T:net@nospam.com>
wrote in message
news:Rhu1f.32218$lq6.15698@fed1read01...
Dear Rod Ryker:
"Rod Ryker" <rryker@fuse.net> wrote in message
news:8570b$4346170c$d8442838$25078@FUSE.NET...
...
Rod: Regardless of how joined, or later when heat is
applied,
the metals are under pressure.
The earth's magnetic field is the applicable reason that a
current flows, and a voltage is measured.
So the effect disappears inside Helmholz coils? I don't think
so.
Rod: If you have a web site confirming an identical experiment
then please share. :)
Although the earth's magnetic field is in effect null
in this scenario, uniform or not, the magnetic pressure from
the
Helmholtz coil pair raises the temperature of the metals.
Since this is a simple request to fulfill:
http://lunar.ksc.nasa.gov/archives/documents/SP4214/SP-4214.pdf
thermocouples function on the Moon, and it has no magentic field
to speak of.
I am not sure if this isn't the same method of powering the
Pioneers (and others)...
But I suppose you could claim that the Sun's magnetic field is
supplying the "magnetic pressure" in this case... if you were
trying to be silly.
David A. Smith
.
|
|
|
| User: "Rod Ryker" |
|
| Title: Re: Bimetallic electrical Potential and conservation of charge |
07 Oct 2005 08:24:44 PM |
|
|
N:dlzc D:aol T:com (dlzc) <N: dlzc1 D:cox T:net@nospam.com> wrote in message
news:gQA1f.36579$lq6.4540@fed1read01...
Dear Rod Ryker:
"Rod Ryker" <rryker@fuse.net> wrote in message
news:d4348$4346c2d2$d8442aed$6932@FUSE.NET...
N:dlzc D:aol T:com (dlzc) <N: dlzc1 D:cox T:net@nospam.com>
wrote in message
news:Rhu1f.32218$lq6.15698@fed1read01...
Dear Rod Ryker:
"Rod Ryker" <rryker@fuse.net> wrote in message
news:8570b$4346170c$d8442838$25078@FUSE.NET...
...
Rod: Regardless of how joined, or later when heat is
applied,
the metals are under pressure.
The earth's magnetic field is the applicable reason that a
current flows, and a voltage is measured.
So the effect disappears inside Helmholz coils? I don't think
so.
Rod: If you have a web site confirming an identical experiment
then please share. :)
Although the earth's magnetic field is in effect null
in this scenario, uniform or not, the magnetic pressure from
the
Helmholtz coil pair raises the temperature of the metals.
Since this is a simple request to fulfill:
http://lunar.ksc.nasa.gov/archives/documents/SP4214/SP-4214.pdf
thermocouples function on the Moon, and it has no magentic field
to speak of.
I am not sure if this isn't the same method of powering the
Pioneers (and others)...
But I suppose you could claim that the Sun's magnetic field is
supplying the "magnetic pressure" in this case... if you were
trying to be silly.
David A. Smith
Rod: EM Waves are more powerfull on the moon
because of the absence of atmosphere.
--
Rod Ryker...
The intricacies of nature is man's cannon fodder.
.
|
|
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| User: "N:dlzc D:aol T:com \dlzc\ N: dlzc1 D:cox" |
|
| Title: Re: Bimetallic electrical Potential and conservation of charge |
07 Oct 2005 10:14:47 PM |
|
|
Dear Rod Ryker:
"Rod Ryker" <rryker@fuse.net> wrote in message
news:36df8$43471fd9$d8442bcb$22590@FUSE.NET...
N:dlzc D:aol T:com (dlzc) <N: dlzc1 D:cox T:net@nospam.com>
wrote in message
news:gQA1f.36579$lq6.4540@fed1read01...
Dear Rod Ryker:
"Rod Ryker" <rryker@fuse.net> wrote in message
news:d4348$4346c2d2$d8442aed$6932@FUSE.NET...
N:dlzc D:aol T:com (dlzc) <N: dlzc1 D:cox T:net@nospam.com>
wrote in message
news:Rhu1f.32218$lq6.15698@fed1read01...
Dear Rod Ryker:
"Rod Ryker" <rryker@fuse.net> wrote in message
news:8570b$4346170c$d8442838$25078@FUSE.NET...
...
Rod: Regardless of how joined, or later when heat is
applied,
the metals are under pressure.
The earth's magnetic field is the applicable reason that
a
current flows, and a voltage is measured.
So the effect disappears inside Helmholz coils? I don't
think
so.
Rod: If you have a web site confirming an identical
experiment
then please share. :)
Although the earth's magnetic field is in effect null
in this scenario, uniform or not, the magnetic pressure from
the
Helmholtz coil pair raises the temperature of the metals.
Since this is a simple request to fulfill:
http://lunar.ksc.nasa.gov/archives/documents/SP4214/SP-4214.pdf
thermocouples function on the Moon, and it has no magentic
field
to speak of.
I am not sure if this isn't the same method of powering the
Pioneers (and others)...
But I suppose you could claim that the Sun's magnetic field is
supplying the "magnetic pressure" in this case... if you were
trying to be silly.
Rod: EM Waves are more powerfull on the moon
because of the absence of atmosphere.
I suspect you are now trolling...
Goodbye.
<plonk>
David A. Smith
.
|
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| User: "Rod Ryker" |
|
| Title: Re: Bimetallic electrical Potential and conservation of charge |
08 Oct 2005 12:08:34 AM |
|
|
"N:dlzc D:aol T:com (dlzc)" <N: dlzc1 D:cox
T:net@nospam.com> wrote in message
news:xQG1f.40474$lq6.6117@fed1read01...
Dear Rod Ryker:
"Rod Ryker" <rryker@fuse.net> wrote in message
news:36df8$43471fd9$d8442bcb$22590@FUSE.NET...
N:dlzc D:aol T:com (dlzc) <N: dlzc1 D:cox
T:net@nospam.com>
wrote in message
news:gQA1f.36579$lq6.4540@fed1read01...
Dear Rod Ryker:
"Rod Ryker" <rryker@fuse.net> wrote in
message
news:d4348$4346c2d2$d8442aed$6932@FUSE.NET...
N:dlzc D:aol T:com (dlzc) <N: dlzc1 D:cox
T:net@nospam.com>
wrote in message
news:Rhu1f.32218$lq6.15698@fed1read01...
Dear Rod Ryker:
"Rod Ryker" <rryker@fuse.net> wrote in
message
news:8570b$4346170c$d8442838$25078@FUSE.NET...
...
Rod: Regardless of how joined, or later
when heat is
applied,
the metals are under pressure.
The earth's magnetic field is the
applicable reason that
a
current flows, and a voltage is
measured.
So the effect disappears inside Helmholz
coils? I don't
think
so.
Rod: If you have a web site confirming an
identical
experiment
then please share. :)
Although the earth's magnetic field is in
effect null
in this scenario, uniform or not, the
magnetic pressure from
the
Helmholtz coil pair raises the temperature
of the metals.
Since this is a simple request to fulfill:
http://lunar.ksc.nasa.gov/archives/documents/SP421
4/SP-4214.pdf
thermocouples function on the Moon, and it
has no magentic
field
to speak of.
I am not sure if this isn't the same method
of powering the
Pioneers (and others)...
But I suppose you could claim that the Sun's
magnetic field is
supplying the "magnetic pressure" in this
case... if you were
trying to be silly.
Rod: EM Waves are more powerfull on the moon
because of the absence of atmosphere.
I suspect you are now trolling...
Goodbye.
<plonk>
David A. Smith
Rod: Of course no Helmholtz experiment as I asked
for re your pdf suggestion. :)
I just read the passages, RTG, the radioisotopes
(EM Waves)
are used to apply a pressure to the thermocouples
resulting in the
production of electricity.
So, your answer to Paul is EM Waves are the
culprit.
--
Rod Ryker...
The intricacies of nature is man's cannon fodder.
.
|
|
|
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| User: "Rod Ryker" |
|
| Title: Re: Bimetallic electrical Potential and conservation of charge |
07 Oct 2005 11:21:03 PM |
|
|
"N:dlzc D:aol T:com (dlzc)" <N: dlzc1 D:cox T:net@nospam.com> wrote in
message news:xQG1f.40474$lq6.6117@fed1read01...
Dear Rod Ryker:
"Rod Ryker" <rryker@fuse.net> wrote in message
news:36df8$43471fd9$d8442bcb$22590@FUSE.NET...
N:dlzc D:aol T:com (dlzc) <N: dlzc1 D:cox T:net@nospam.com>
wrote in message
news:gQA1f.36579$lq6.4540@fed1read01...
Dear Rod Ryker:
"Rod Ryker" <rryker@fuse.net> wrote in message
news:d4348$4346c2d2$d8442aed$6932@FUSE.NET...
N:dlzc D:aol T:com (dlzc) <N: dlzc1 D:cox T:net@nospam.com>
wrote in message
news:Rhu1f.32218$lq6.15698@fed1read01...
Dear Rod Ryker:
"Rod Ryker" <rryker@fuse.net> wrote in message
news:8570b$4346170c$d8442838$25078@FUSE.NET...
...
Rod: Regardless of how joined, or later when heat is
applied,
the metals are under pressure.
The earth's magnetic field is the applicable reason that
a
current flows, and a voltage is measured.
So the effect disappears inside Helmholz coils? I don't
think
so.
Rod: If you have a web site confirming an identical
experiment
then please share. :)
Although the earth's magnetic field is in effect null
in this scenario, uniform or not, the magnetic pressure from
the
Helmholtz coil pair raises the temperature of the metals.
Since this is a simple request to fulfill:
http://lunar.ksc.nasa.gov/archives/documents/SP4214/SP-4214.pdf
thermocouples function on the Moon, and it has no magentic
field
to speak of.
I am not sure if this isn't the same method of powering the
Pioneers (and others)...
But I suppose you could claim that the Sun's magnetic field is
supplying the "magnetic pressure" in this case... if you were
trying to be silly.
Rod: EM Waves are more powerfull on the moon
because of the absence of atmosphere.
I suspect you are now trolling...
Goodbye.
<plonk>
David A. Smith
Rod: No, not trolling.
The pdf has 404 pages.
You gave me no specific passage.
And I have 56k dial up, so it would take awhile.
However, I decided to dl it and read it.
I'll have an argument tomorrow, unless... :)
--
Rod Ryker...
The intricacies of nature is man's cannon fodder.
.
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| User: "Rod Ryker" |
|
| Title: Re: Bimetallic electrical Potential and conservation of charge |
05 Oct 2005 11:33:47 PM |
|
|
Paul Stowe <TheAetherist@best.net> wrote in message
news:ng49k1lf7fecmsa8g239ehml2lb7f1necl@4ax.com...
As Volta demonstrated in the last decade of the 18th century when
two different metals are brought into physical contact (even when
both are, to all measurable detectability, electrically neutral,
a.k.a. no measurable potential) there will be generated a constant
and measurable non-zero Potential at the two opposing ends of the
bimetallic coupling. To my understanding, as long as no electrolyte
is present the metals are not be affected by any continuous circuit
created in this fashion. Now to my question,
Given that both metals are/were initially electrically neutral and
assuming conservation of charge, what creates and maintains the
measured Potential?
Paul Stowe
Rod: The Seebeck Effect, as long as the metals remain at
an constant temperature.
--
Rod Ryker...
The intricacies of nature is man's cannon fodder.
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| User: "Uncle Al" |
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| Title: Re: Bimetallic electrical Potential and conservation of charge |
06 Oct 2005 12:47:42 PM |
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Paul Stowe wrote:
As Volta demonstrated in the last decade of the 18th century when
two different metals are brought into physical contact (even when
both are, to all measurable detectability, electrically neutral,
a.k.a. no measurable potential) there will be generated a constant
and measurable non-zero Potential at the two opposing ends of the
bimetallic coupling. To my understanding, as long as no electrolyte
is present the metals are not be affected by any continuous circuit
created in this fashion. Now to my question,
Given that both metals are/were initially electrically neutral and
assuming conservation of charge, what creates and maintains the
measured Potential?
Fermi levels if you are solid state with band structure. LUMO and
HOMO if you are a chemist with discrete molecular orbitals. Works for
dielectrics, too - tribocharging. The lowest energy contact state is
charge-separated. Look at the depletion region of a diode interface.
None of this stuff is new.
A diamond (intrinsic dielectric or boron-doped p-semiconducting) has a
negative work function for electron emission into vacuum.
Thermodynamics has no problem with that. The books still balance -
it's a heat engine.
(Given inert atmosphere in all cases) A lump of graphite at 1000 C is
a bright emitter, as the blackbody curve will tell you. Transparent
glass, a mirror, and colorless gas will be poor emitters, as the First
Law of Thermodynamics will tell you. White diamond at 1000 C won't
emit blackbody radiation worth a damn - and you need quantum mechanics
to explain that one. It's still not a problem.
--
Uncle Al
http://www.mazepath.com/uncleal/
(Toxic URL! Unsafe for children and most mammals)
http://www.mazepath.com/uncleal/qz.pdf
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