| Topic: |
Science > Physics |
| User: |
"Jeff" |
| Date: |
01 Jul 2006 07:11:41 AM |
| Object: |
preventing corrosion |
I'd like to build a few solar (water) collectors. With the price of
copper as high as it is, this makes steel conduit seem very attractive.
Thermal losses of using steel over copper would just be a bit less than
a degree F.
So... This is effectively a closed system where the working fluid is
recycled. How do I keep the steel from corroding, rusting or just
building up deposits? What treatment to the water would be effective? Is
this a case for a water softener?
Jeff
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| User: "Znod Grimpo" |
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| Title: Re: preventing corrosion |
01 Jul 2006 09:54:04 PM |
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"Jeff" <dont_bug_me@all.uk> wrote in message
news:1Etpg.976$cd3.392@newsread3.news.pas.earthlink.net...
I'd like to build a few solar (water) collectors. With the price of
copper as high as it is, this makes steel conduit seem very attractive.
Thermal losses of using steel over copper would just be a bit less than a
degree F.
So... This is effectively a closed system where the working fluid is
recycled. How do I keep the steel from corroding, rusting or just building
up deposits? What treatment to the water would be effective? Is this a
case for a water softener?
Jeff
do a survey of the industry
most use copper for several reasons.
corrosion, thermal conductivity, sealing via solder, fin attachment, higher
efficiency
water softener is a salt that causes corrosion
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| User: "Jeff" |
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| Title: Re: preventing corrosion |
02 Jul 2006 01:15:43 PM |
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Znod Grimpo wrote:
"Jeff" <dont_bug_me@all.uk> wrote in message
news:1Etpg.976$cd3.392@newsread3.news.pas.earthlink.net...
I'd like to build a few solar (water) collectors. With the price of
copper as high as it is, this makes steel conduit seem very attractive.
Thermal losses of using steel over copper would just be a bit less than a
degree F.
So... This is effectively a closed system where the working fluid is
recycled. How do I keep the steel from corroding, rusting or just building
up deposits? What treatment to the water would be effective? Is this a
case for a water softener?
Jeff
do a survey of the industry
most use copper for several reasons.
I only have one problem with copper. The cost of the copper tubing is
greater than the cost of all the other materials combined, by some
margin! Copper is 5 times the price it was a year and a half ago.
The loss due to the steel pipe is fairly small, figure steel at I
think 26 BTU Ft/Ft2 F
corrosion, thermal conductivity, sealing via solder, fin attachment,
Actually wasn't planning on soldering the aluminum fins on. Heatsink
compound and rivits with a backing plate. Black etch primer on both to
prevent contact elctrolysis and for the collector surface.
higher
efficiency
water softener is a salt that causes corrosion
Good point.
I'm tempted to try the galvanized steel conduit and filtered tap water.
I'm thinking the amount of scale formation in a few hundred gallons of
water is small compared to what formed the scale in my old steel
plumbing over decades.
I don't care if this doesn't last years as I think the cost of
selective coatings will fall with the introduction of "Black Crystal". I
can just toss out the fin assemblies and upgrade, keeping the box and
glazing. There's a fair number of manufacturers that make replacement
assemblies for solar water collectors. Money is tight, for me, for a
while...
Jeff
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| User: "Znod Grimpo" |
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| Title: Re: preventing corrosion |
02 Jul 2006 02:53:50 PM |
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"Jeff" <dont_bug_me@all.uk> wrote in message
news:j3Upg.1891$PE1.260@newsread2.news.pas.earthlink.net...
Znod Grimpo wrote:
"Jeff" <dont_bug_me@all.uk> wrote in message
news:1Etpg.976$cd3.392@newsread3.news.pas.earthlink.net...
I'd like to build a few solar (water) collectors. With the price of
copper as high as it is, this makes steel conduit seem very attractive.
Thermal losses of using steel over copper would just be a bit less than
a degree F.
So... This is effectively a closed system where the working fluid is
recycled. How do I keep the steel from corroding, rusting or just
building up deposits? What treatment to the water would be effective? Is
this a case for a water softener?
Jeff
do a survey of the industry
most use copper for several reasons.
I only have one problem with copper. The cost of the copper tubing is
greater than the cost of all the other materials combined, by some margin!
Copper is 5 times the price it was a year and a half ago.
The loss due to the steel pipe is fairly small, figure steel at I think
26 BTU Ft/Ft2 F
corrosion, thermal conductivity, sealing via solder, fin attachment,
Actually wasn't planning on soldering the aluminum fins on. Heatsink
compound and rivits with a backing plate. Black etch primer on both to
prevent contact elctrolysis and for the collector surface.
higher
efficiency
water softener is a salt that causes corrosion
Good point.
I'm tempted to try the galvanized steel conduit and filtered tap water.
I'm thinking the amount of scale formation in a few hundred gallons of
water is small compared to what formed the scale in my old steel plumbing
over decades.
I don't care if this doesn't last years as I think the cost of selective
coatings will fall with the introduction of "Black Crystal". I can just
toss out the fin assemblies and upgrade, keeping the box and glazing.
There's a fair number of manufacturers that make replacement assemblies
for solar water collectors. Money is tight, for me, for a while...
the Israelis have cheap solar collector down cold.
you could use that black plastic pipe, not use fins, I have seen several
that just have lots of black plastic pipe stacked on the back.
(it is very cheap, low pressure stuff) No corrosion problems.
Guess if you make it out of very cheap stuff, it will be low cost to
replace items in it.
There are some good pumps out there too, cost $100 or so but use hardly any
electricity, could use DC from a panel, or use the self cirullating setup,
tank higher than the panel.
galvenized pipe will be heavy
there is AL pipe out there too, but I havent worked with it much.
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| User: "Jeff" |
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| Title: Re: preventing corrosion |
02 Jul 2006 07:43:37 PM |
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Znod Grimpo wrote:
"Jeff" <dont_bug_me@all.uk> wrote in message
news:j3Upg.1891$PE1.260@newsread2.news.pas.earthlink.net...
Znod Grimpo wrote:
"Jeff" <dont_bug_me@all.uk> wrote in message
news:1Etpg.976$cd3.392@newsread3.news.pas.earthlink.net...
I'd like to build a few solar (water) collectors. With the price of
copper as high as it is, this makes steel conduit seem very attractive.
Thermal losses of using steel over copper would just be a bit less than
a degree F.
So... This is effectively a closed system where the working fluid is
recycled. How do I keep the steel from corroding, rusting or just
building up deposits? What treatment to the water would be effective? Is
this a case for a water softener?
Jeff
do a survey of the industry
most use copper for several reasons.
I only have one problem with copper. The cost of the copper tubing is
greater than the cost of all the other materials combined, by some margin!
Copper is 5 times the price it was a year and a half ago.
The loss due to the steel pipe is fairly small, figure steel at I think
26 BTU Ft/Ft2 F
corrosion, thermal conductivity, sealing via solder, fin attachment,
Actually wasn't planning on soldering the aluminum fins on. Heatsink
compound and rivits with a backing plate. Black etch primer on both to
prevent contact elctrolysis and for the collector surface.
higher
efficiency
water softener is a salt that causes corrosion
Good point.
I'm tempted to try the galvanized steel conduit and filtered tap water.
I'm thinking the amount of scale formation in a few hundred gallons of
water is small compared to what formed the scale in my old steel plumbing
over decades.
I don't care if this doesn't last years as I think the cost of selective
coatings will fall with the introduction of "Black Crystal". I can just
toss out the fin assemblies and upgrade, keeping the box and glazing.
There's a fair number of manufacturers that make replacement assemblies
for solar water collectors. Money is tight, for me, for a while...
the Israelis have cheap solar collector down cold.
you could use that black plastic pipe, not use fins, I have seen several
that just have lots of black plastic pipe stacked on the back.
I'm guessing that this is unglazed, stagnation temps for glazed could be
a killer. The figures I have for CPVC is a vicat softening point of 189
to 284 F and an "R" value of ~1 BTU in/hr Ft2 F
With a .1" tubing wall and about 250 BTU/Ft2 Hr that would be roughly a
15F temperature loss across the tubing wall, perhaps not bad.
Thanks,
Jeff
(it is very cheap, low pressure stuff) No corrosion problems.
Guess if you make it out of very cheap stuff, it will be low cost to
replace items in it.
There are some good pumps out there too, cost $100 or so but use hardly any
electricity, could use DC from a panel, or use the self cirullating setup,
tank higher than the panel.
galvenized pipe will be heavy
there is AL pipe out there too, but I havent worked with it much.
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| User: "tadchem" |
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| Title: Re: preventing corrosion |
02 Jul 2006 05:26:47 PM |
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Jeff wrote:
I only have one problem with copper. The cost of the copper tubing is
greater than the cost of all the other materials combined, by some
margin! Copper is 5 times the price it was a year and a half ago.
Copper can corrode, too. This often occurs in copper pipes carrying
water:
http://www.southeastwater.com.au/sewl/index.asp?link_id=30.381
corrosion, thermal conductivity, sealing via solder, fin attachment,
Actually wasn't planning on soldering the aluminum fins on.
I hope not. Solder doesn't work on aluminum at all. Aluminum coats
its own surface with a molecular layer of aluminum oxide, which
inhibits further reactions with air. Solder doesn't stick to *aluminum
oxide*. It is possible to weld aluminum, but it requires arc welding
in an inert atmosphere.
Heatsink
compound and rivits
....either rivets or bolts. Simple sheet metal screws will work loose
as vibration reshapes the aluminum threads.
with a backing plate. Black etch primer on both to
prevent contact elctrolysis and for the collector surface.
Junction potentials are seen with dissimilar metals only. Stick with
only one metal for construction and you won't have to worry about
eletrolysis.
I'm tempted to try the galvanized steel conduit
Galvanized steel 'fights' corrosion by providing a more active metal
(zinc) which is guaranteed to corrode before the iron in the steel
begins to show corrosion. You will be adding zinc to your water.
and filtered tap water.
Filtering tap water will remove the solids and the particulates, but
very little of the dissolved gases (oxidizers) and mineral salts
(electrolytes) that will contribute to corrosion. If this is to be a
closed system I suggest using water that has been distilled *and*
degassed.
I'm thinking the amount of scale formation in a few hundred gallons of
water is small compared to what formed the scale in my old steel
plumbing over decades.
Scale often acts like seeds: once it is planted it grows. It's
'nutrients' are the metal, the air, and the water.
I don't care if this doesn't last years as I think the cost of
selective coatings will fall with the introduction of "Black Crystal". I
can just toss out the fin assemblies and upgrade,
Fin assemblies are a function of design, which is driven by function
and performance demands. A sexy new coating is not going to eliminate
the need for fins in any application where they are required
(high-efficiency heat exchangers, especially systems in which one of
the working fluids is gas phase.)
Money is tight, for me, for a
while...
It is tight for most physicists, and has been for *quite* a while.
Tom Davidson
Richmond, VA
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| User: "" |
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| Title: Re: preventing corrosion |
02 Jul 2006 06:45:02 PM |
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In sci.physics tadchem <tadchem@comcast.net> wrote:
<snip>
I hope not. Solder doesn't work on aluminum at all. Aluminum coats
its own surface with a molecular layer of aluminum oxide, which
inhibits further reactions with air. Solder doesn't stick to *aluminum
oxide*. It is possible to weld aluminum, but it requires arc welding
in an inert atmosphere.
Materials to solder, braze, and weld (both gas and arc) aluminum have
been available for decades now.
Consult a McMaster-Carr catalog.
<snip remaining>
--
Jim Pennino
Remove .spam.sux to reply.
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| User: "Jeff" |
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| Title: Re: preventing corrosion |
02 Jul 2006 08:02:49 PM |
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tadchem wrote:
Jeff wrote:
I only have one problem with copper. The cost of the copper tubing is
greater than the cost of all the other materials combined, by some
margin! Copper is 5 times the price it was a year and a half ago.
Copper can corrode, too. This often occurs in copper pipes carrying
water:
http://www.southeastwater.com.au/sewl/index.asp?link_id=30.381
corrosion, thermal conductivity, sealing via solder, fin attachment,
Actually wasn't planning on soldering the aluminum fins on.
I hope not. Solder doesn't work on aluminum at all. Aluminum coats
its own surface with a molecular layer of aluminum oxide, which
inhibits further reactions with air. Solder doesn't stick to *aluminum
oxide*. It is possible to weld aluminum, but it requires arc welding
in an inert atmosphere.
Heatsink
compound and rivits
...either rivets or bolts. Simple sheet metal screws will work loose
as vibration reshapes the aluminum threads.
with a backing plate. Black etch primer on both to
prevent contact elctrolysis and for the collector surface.
Junction potentials are seen with dissimilar metals only. Stick with
only one metal for construction and you won't have to worry about
eletrolysis.
Aluminum comes to mind, but I haven't found a source for it. I live in a
fairly large city, but it is amazing what is hard to come by.
How do think aluminum would do? Nothing will be potable.
I'm tempted to try the galvanized steel conduit
Galvanized steel 'fights' corrosion by providing a more active metal
(zinc) which is guaranteed to corrode before the iron in the steel
begins to show corrosion. You will be adding zinc to your water.
Sounds like I will run out of zinc in short order!
and filtered tap water.
Filtering tap water will remove the solids and the particulates, but
very little of the dissolved gases (oxidizers) and mineral salts
(electrolytes) that will contribute to corrosion. If this is to be a
closed system I suggest using water that has been distilled *and*
degassed.
I think the cost of several hundred gallons of distilled water is
greater than the copper!
I'm thinking the amount of scale formation in a few hundred gallons of
water is small compared to what formed the scale in my old steel
plumbing over decades.
Scale often acts like seeds: once it is planted it grows. It's
'nutrients' are the metal, the air, and the water.
Got it.
I don't care if this doesn't last years as I think the cost of
selective coatings will fall with the introduction of "Black Crystal". I
can just toss out the fin assemblies and upgrade,
Fin assemblies are a function of design, which is driven by function
and performance demands.
<URL: sel.me.wisc.edu/codepro/new_codepro.html />
A sexy new coating is not going to eliminate
the need for fins in any application where they are required
(high-efficiency heat exchangers, especially systems in which one of
the working fluids is gas phase.)
Nope, but the current selective coatings are expensive. Selective
coatings improve performance in marginal conditions or where the
temperature of the working fluid to ambient is great. For solar
collectors this usually is referred to as instantaneous efficiency and
is related to T working - T ambient / Solar Insolation (in BTU/Ft2 or
KWHr/M2)
I've always been a believer in not buying the latest greatest when
you can get something better later for less than half the price.
Money is tight, for me, for a
while...
It is tight for most physicists, and has been for *quite* a while.
For me it was a couple years of helping take care of Mom while she was
on the way out. But I get your point!
Cheers,
Jeff
Tom Davidson
Richmond, VA
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| User: "" |
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| Title: Re: preventing corrosion |
02 Jul 2006 10:35:03 PM |
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In sci.physics Jeff <dont_bug_me@all.uk> wrote:
<snip>
Aluminum comes to mind, but I haven't found a source for it. I live in a
fairly large city, but it is amazing what is hard to come by.
How do think aluminum would do? Nothing will be potable.
Aluminum pipe/tubing is more expensive than the corresponding thing
in copper, at least in the US.
<snip>
I think the cost of several hundred gallons of distilled water is
greater than the copper!
Don't know about the UK, but in the US distilled water can be had
in supermarkets for about $1/gal.
Making your own (assuming you don't need lab grade) is fairly simple
with a solar still if you have patience.
<snip>
In the US there is an outfit called McMaster-Carr where you go look
for stuff like this.
http://www.mcmaster.com/
While the absolute price will probably be different in the UK, the
relative price is probably about the same.
Or better, do a search for a similar industrial supply house in the UK.
Such a supplier is good for finding out what is commercially available
and the rough price if nothing else.
--
Jim Pennino
Remove .spam.sux to reply.
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| User: "Jeff" |
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| Title: Re: preventing corrosion |
08 Jul 2006 01:04:37 AM |
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wrote:
In sci.physics Jeff <dont_bug_me@all.uk> wrote:
<snip>
Aluminum comes to mind, but I haven't found a source for it. I live in a
fairly large city, but it is amazing what is hard to come by.
How do think aluminum would do? Nothing will be potable.
Aluminum pipe/tubing is more expensive than the corresponding thing
in copper, at least in the US.
I see that. I find it interesting because the price of copper is 3 times
that of aluminum. Obviously there is something else going on.
<snip>
I think the cost of several hundred gallons of distilled water is
greater than the copper!
Don't know about the UK, but in the US distilled water can be had
in supermarkets for about $1/gal.
I can understand why you think I'm in the UK from my munged email, but
I'm in Atlanta, Ga.
Making your own (assuming you don't need lab grade) is fairly simple
with a solar still if you have patience.
<snip>
In the US there is an outfit called McMaster-Carr where you go look
for stuff like this.
http://www.mcmaster.com/
While the absolute price will probably be different in the UK, the
relative price is probably about the same.
Or better, do a search for a similar industrial supply house in the UK.
Such a supplier is good for finding out what is commercially available
and the rough price if nothing else.
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| User: "" |
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| Title: Re: preventing corrosion |
01 Jul 2006 11:45:02 AM |
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In sci.physics Jeff <dont_bug_me@all.uk> wrote:
I'd like to build a few solar (water) collectors. With the price of
copper as high as it is, this makes steel conduit seem very attractive.
Thermal losses of using steel over copper would just be a bit less than
a degree F.
So... This is effectively a closed system where the working fluid is
recycled. How do I keep the steel from corroding, rusting or just
building up deposits? What treatment to the water would be effective? Is
this a case for a water softener?
Jeff
De-oxygenated, distilled water for the inside and epoxy paint or zinc plate
for the outside.
Or stainless steel plumbing.
Or use copper tubing which is a lot cheaper than copper pipe.
--
Jim Pennino
Remove .spam.sux to reply.
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| User: "tadchem" |
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| Title: Re: preventing corrosion |
01 Jul 2006 12:13:56 PM |
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Jeff wrote:
I'd like to build a few solar (water) collectors. With the price of
copper as high as it is, this makes steel conduit seem very attractive.
Thermal losses of using steel over copper would just be a bit less than
a degree F.
So... This is effectively a closed system where the working fluid is
recycled. How do I keep the steel from corroding, rusting or just
building up deposits? What treatment to the water would be effective? Is
this a case for a water softener?
Jeff
If I understand you correctly, you plan to use these to collect solar
energy as heat using water as a working fluid.
There are three ingredients to corrosion: an active metal, an oxidizer,
and a hydroscopic fluid. You can demonstrate this to yourself by
watching a drop of water evaporate on a degreased iron skillet - the
rust forms where the water and air *both* touch the metal.
In your case these three ingredients are steel, air, and water
respectively.
You could slow the corrosion using $tainless $teel.
You purge the air from the system (including the fluid) and could
encapsulate the apparatus in an inert atmosphere (rarely practical).
You could change your fluid to something not hydroscopic (like oil).
You would still need to protect the system from contact with water from
external sources (precipitation, condensation).
Water 'treatments' are rarely effective as it is usually the water
itself that is part of the problem. I used to work with a system using
chlorine, antimony pentachloride (SbCl5 - a superacid and a very
powerful oxidizer) and Monel (a copper-nickel alloy developed for
corrosion resistance). As long as we kept the SbCl5 scrupulously dry
all was well, but even a fraction of a percent of water was enough to
eat a hole through the Monel 'pot' - shutting down production for weeks
and requiring a $30,000 replacement.
Corrosion control through water treatment is usually done only for
industrial steam systems, and the treatments are intended to coat the
interior of the plumbing with a barrier to prevent water from coming
directly into contact with the metal.
HTH
Tom Davidson
Richmond, VA
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| User: "Timo A. Nieminen" |
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| Title: Re: preventing corrosion |
01 Jul 2006 03:26:28 PM |
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On Sat, 1 Jul 2006, Jeff wrote:
I'd like to build a few solar (water) collectors. With the price of copper
as high as it is, this makes steel conduit seem very attractive. Thermal
losses of using steel over copper would just be a bit less than a degree F.
So... This is effectively a closed system where the working fluid is
recycled. How do I keep the steel from corroding, rusting or just building up
deposits? What treatment to the water would be effective? Is this a case for
a water softener?
Closed system, sounds like a car radiator. Perhaps some of the products
for such might be good?
--
Timo Nieminen - Home page: http://www.physics.uq.edu.au/people/nieminen/
E-prints: http://eprint.uq.edu.au/view/person/Nieminen,_Timo_A..html
Shrine to Spirits: http://www.users.bigpond.com/timo_nieminen/spirits.html
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