System boundary



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Topic: Science > Physics
User: "Haines Brown"
Date: 05 Jun 2007 12:01:06 PM
Object: System boundary
I'm trying to grasp the broader ontological implications of a system
boundary as described in physics. I'd appreciate knowing if you think
any of the following propositions are incorrect or inaccurate.
1. The notion of "systemness" implies the existence of a boundary
between the system and its environment. In the absence of a
boundary, there is no system and hence no definition of system
state. Boundary is what makes the system an entity that has
properties.
2. The boundary is a structure (material or forcefield), that allows
matter or energy having certain characteristics to pass or be
blocked in the passage from the system to its environment.
3. The minimalist functional definition of such a boundary is that it
limits the system's degrees of freedom/phase-space.
4. This phase-space is a description of all possible system states,
and it can either be inferred from multiple observations of system
outcomes, or it can be represented as being real potencies present
in the system. Representing the boundary as limiting phase-space
implies that this distribution of possible outcomes is being acted
upon and therefore these are real unobservable potencies that exist
independently of our observations.
5. Presumably the different states described as the system's
phase-space each have different probabilities, which are a function
of the path necessary to arrive at them. Therefore, the boundary
can be functionally described more accurately as constraining the
probability distribution of the system's possible outcomes.
6. A causal influence upon a system that comes from its environment
necessarily does work on the system to change its state. A boundary
does not do work, but defines how the work is done by the causal
agent.
7. The boundary may allow the "export of entropy" into the system's
environment, in which case the system looses entropy. This "export
of entropy" means that the selective function of the boundary is
such that it diffuses heat or disordered matter into the system's
environment.
--

Haines Brown, KB1GRM


.

User: "PD"

Title: Re: System boundary 05 Jun 2007 05:47:08 PM
On Jun 5, 12:01 pm, Haines Brown <bro...@teufel.hartford-hwp.com>
wrote:

I'm trying to grasp the broader ontological implications of a system
boundary as described in physics.

There are no ontological implications. It is a definition, associating
a connotation to a word, and therefore it may have semantic
implications. Not ontological ones, though. "Ontological" is a pretty
word, though, and I'm sure I would use it at every opportunity too, if
given the chance.

I'd appreciate knowing if you think
any of the following propositions are incorrect or inaccurate.

1. The notion of "systemness" implies the existence of a boundary
between the system and its environment. In the absence of a
boundary, there is no system and hence no definition of system
state. Boundary is what makes the system an entity that has
properties.

OK.


2. The boundary is a structure (material or forcefield), that allows
matter or energy having certain characteristics to pass or be
blocked in the passage from the system to its environment.

Nope. This is plain wrong. It is a mental dotted line, that's it.
Nothing complicated or even ontological about it.


3. The minimalist functional definition of such a boundary is that it
limits the system's degrees of freedom/phase-space.

This is also wrong. A system can have unrestricted degrees of freedom
and still have a mental dotted line around it.


4. This phase-space is a description of all possible system states,
and it can either be inferred from multiple observations of system
outcomes, or it can be represented as being real potencies present
in the system. Representing the boundary as limiting phase-space
implies that this distribution of possible outcomes is being acted
upon and therefore these are real unobservable potencies that exist
independently of our observations.

Well, since both 2 and 3 are wrong, it is plain that 4, 5, 6, and 7
(which follow from 2 and 3) are also wrong.
Perhaps if you started over following (1) and tried again.
PD


5. Presumably the different states described as the system's
phase-space each have different probabilities, which are a function
of the path necessary to arrive at them. Therefore, the boundary
can be functionally described more accurately as constraining the
probability distribution of the system's possible outcomes.

6. A causal influence upon a system that comes from its environment
necessarily does work on the system to change its state. A boundary
does not do work, but defines how the work is done by the causal
agent.

7. The boundary may allow the "export of entropy" into the system's
environment, in which case the system looses entropy. This "export
of entropy" means that the selective function of the boundary is
such that it diffuses heat or disordered matter into the system's
environment.

--

Haines Brown, KB1GRM

.
User: "Haines Brown"

Title: Re: System boundary 06 Jun 2007 05:08:18 AM
PD <TheDraperFamily@gmail.com> writes:

On Jun 5, 12:01 pm, Haines Brown <bro...@teufel.hartford-hwp.com>
wrote:

I'm trying to grasp the broader ontological implications of a
system boundary as described in physics.


There are no ontological implications. It is a definition, associating
a connotation to a word, and therefore it may have semantic
implications. Not ontological ones, though.

2. The boundary is a structure (material or forcefield), that allows
matter or energy having certain characteristics to pass or be
blocked in the passage from the system to its environment.


Nope. This is plain wrong. It is a mental dotted line, that's it.
Nothing complicated or even ontological about it.

No, I'll stick with "ontological". The reason is simple, in that I
don't adopt a postmodern view that all statements necessarily lack
truth value. Most physicists are not postmodern, and they assume that
a boundary (wall, membrane, mediation), has some objective reality. It
is not a very helpful critique of a set of propositions to argue that
everything is fiction and so there's no point in having offered them
in the first place.
How can I justify the proposition? I suppose by referring to an
authority. For example that old classic, Foundations of Physics by
Robert Linsay and Henry Margenau (1938). In Section 1.9, they
discusses specific and general boundary conditions at length. While
the description of a system state engages a subjective element (such
as specifying the space-time frame so that the system becomes
measurable), the authors assume there is nevertheless a truth value
in that description; boundaries are real. "... specific boundary
conditions are customarily in physical texts referred to as 'initial'
conditions ..."
Nowadays we are less fixated than the authors on closed systems. For
example, Prigogine's open systems remain systems because they are
distinguished from their environment by their maintenance of a
far-from-equilibrium state. Such a system is obviously not merely the
effect of our subjective viewpoint. I happen to be such a system and I
well know that I exist as a living organism.
This is not the place to discuss the merits and demerits of
postmodernism, but I believe that because it represents a view not
widely shared in the scientific community (unlike the political
community these days), it must be accompanied with some justification
before it can be used to dismiss the common-sense view that our
statements about things are nothing more than fictions.

3. The minimalist functional definition of such a boundary is that it
limits the system's degrees of freedom/phase-space.


This is also wrong. A system can have unrestricted degrees of freedom
and still have a mental dotted line around it.

Of course. Since you reduce boundary to a fiction, it has no effect on
the system.
Again, quoting the text cited above: "... we see the significance of
general boundary conditions: they impose fundamental restrictions on
the type of activity possible for the system considered" (pg. 53).
Clearly, the authors differ with you here. That does not mean they are
right and you wrong, but only that if you choose to differ with a
convention or authority, you need some justification for doing so.

4. This phase-space is a description of all possible system
states, and it can either be inferred from multiple observations
of system outcomes, or it can be represented as being real
potencies present in the system. Representing the boundary as
limiting phase-space implies that this distribution of possible
outcomes is being acted upon and therefore these are real
unobservable potencies that exist independently of our
observations.


Well, since both 2 and 3 are wrong, it is plain that 4, 5, 6, and 7
(which follow from 2 and 3) are also wrong.

I did not say I was offering a set of mutually dependent syllogisms,
but merely independent propositions. Except for the reality of systems
posited in #1, each hopefully stood on its own. Admittedly, item 4
(presuming scientific realism) and 5 (presuming probabilistic
causality) adopt minority views, but these positions are taken
seriously these days. Other than that, as I state in the line you
quote at the beginning, I was merely trying to explicate
the convention, not arguing a case of my own.
--

Haines Brown, KB1GRM


.
User: "PD"

Title: Re: System boundary 06 Jun 2007 06:02:31 AM
On Jun 6, 5:08 am, Haines Brown <bro...@teufel.hartford-hwp.com>
wrote:

PD <TheDraperFam...@gmail.com> writes:

On Jun 5, 12:01 pm, Haines Brown <bro...@teufel.hartford-hwp.com>
wrote:

I'm trying to grasp the broader ontological implications of a
system boundary as described in physics.


There are no ontological implications. It is a definition, associating
a connotation to a word, and therefore it may have semantic
implications. Not ontological ones, though.

2. The boundary is a structure (material or forcefield), that allows
matter or energy having certain characteristics to pass or be
blocked in the passage from the system to its environment.


Nope. This is plain wrong. It is a mental dotted line, that's it.
Nothing complicated or even ontological about it.


No, I'll stick with "ontological". The reason is simple, in that I
don't adopt a postmodern view that all statements necessarily lack
truth value. Most physicists are not postmodern, and they assume that
a boundary (wall, membrane, mediation), has some objective reality. It
is not a very helpful critique of a set of propositions to argue that
everything is fiction and so there's no point in having offered them
in the first place.

How can I justify the proposition? I suppose by referring to an
authority. For example that old classic, Foundations of Physics by
Robert Linsay and Henry Margenau (1938). In Section 1.9, they
discusses specific and general boundary conditions at length. While
the description of a system state engages a subjective element (such
as specifying the space-time frame so that the system becomes
measurable), the authors assume there is nevertheless a truth value
in that description; boundaries are real. "... specific boundary
conditions are customarily in physical texts referred to as 'initial'
conditions ..."

Nowadays we are less fixated than the authors on closed systems. For
example, Prigogine's open systems remain systems because they are
distinguished from their environment by their maintenance of a
far-from-equilibrium state. Such a system is obviously not merely the
effect of our subjective viewpoint. I happen to be such a system and I
well know that I exist as a living organism.

This is not the place to discuss the merits and demerits of
postmodernism, but I believe that because it represents a view not
widely shared in the scientific community (unlike the political
community these days), it must be accompanied with some justification
before it can be used to dismiss the common-sense view that our
statements about things are nothing more than fictions.

3. The minimalist functional definition of such a boundary is that it
limits the system's degrees of freedom/phase-space.


This is also wrong. A system can have unrestricted degrees of freedom
and still have a mental dotted line around it.


Of course. Since you reduce boundary to a fiction, it has no effect on
the system.

Again, quoting the text cited above: "... we see the significance of
general boundary conditions: they impose fundamental restrictions on
the type of activity possible for the system considered" (pg. 53).

Clearly, the authors differ with you here. That does not mean they are
right and you wrong, but only that if you choose to differ with a
convention or authority, you need some justification for doing so.

4. This phase-space is a description of all possible system
states, and it can either be inferred from multiple observations
of system outcomes, or it can be represented as being real
potencies present in the system. Representing the boundary as
limiting phase-space implies that this distribution of possible
outcomes is being acted upon and therefore these are real
unobservable potencies that exist independently of our
observations.


Well, since both 2 and 3 are wrong, it is plain that 4, 5, 6, and 7
(which follow from 2 and 3) are also wrong.


I did not say I was offering a set of mutually dependent syllogisms,
but merely independent propositions. Except for the reality of systems
posited in #1, each hopefully stood on its own. Admittedly, item 4
(presuming scientific realism) and 5 (presuming probabilistic
causality) adopt minority views, but these positions are taken
seriously these days. Other than that, as I state in the line you
quote at the beginning, I was merely trying to explicate
the convention, not arguing a case of my own.

--

Haines Brown, KB1GRM

Well, your babble-generator certainly starts easily with a light pull,
doesn't it? You've read too much and learned too little. It might be
useful to talk with a *physicist* to understand the difference between
a system boundary and where a boundary condition applies. Those are
two different contexts that are sometimes but not often connected.
PD
PD
.
User: "Puppet_Sock"

Title: Re: System boundary 06 Jun 2007 10:04:45 AM
On Jun 6, 7:02 am, PD <TheDraperFam...@gmail.com> wrote:
[snip]

Well, your babble-generator certainly starts easily with a light pull,
doesn't it?

Heh heh. That's excellent!

You've read too much and learned too little. It might be
useful to talk with a *physicist* to understand the difference between
a system boundary and where a boundary condition applies. Those are
two different contexts that are sometimes but not often connected.

In the "mind" of a philosopher, the word in common is enough.
This is a tradition at least as old as Kant. Give a word a complex
technical definition, don't give a complete and simple explanation
of that definition, then arbitrarily and unannounced switch back
and forth between the standard definition and the private technical
one. That way you can "prove" just about anything.
For another example, refer to the interminable threads in sci.math
about 0.999... being not equal to 1. It's a dodge that only a sick
mind, or a philosopher, would use. But the philosophers use it
all of the time as their first opening gambit.
It's word salad. And it's a useless meaningless task.
Socks
.

User: "Haines Brown"

Title: Re: System boundary 06 Jun 2007 03:43:48 PM
PD <TheDraperFamily@gmail.com> writes:

Well, your babble-generator certainly starts easily with a light pull,
doesn't it? You've read too much and learned too little. It might be
useful to talk with a *physicist* to understand the difference between
a system boundary and where a boundary condition applies. Those are
two different contexts that are sometimes but not often connected.

OK, since you are making a pronoucement on elementary physics, and you
feel that only physicists are in a position to do so, I can only infer
you are a physicist. As such you are in a position to define boundary
and boundary condition. Please do so.
--

Haines Brown, KB1GRM


.
User: "PD"

Title: Re: System boundary 07 Jun 2007 09:50:21 AM
On Jun 6, 3:43 pm, Haines Brown <bro...@teufel.hartford-hwp.com>
wrote:

PD <TheDraperFam...@gmail.com> writes:

Well, your babble-generator certainly starts easily with a light pull,
doesn't it? You've read too much and learned too little. It might be
useful to talk with a *physicist* to understand the difference between
a system boundary and where a boundary condition applies. Those are
two different contexts that are sometimes but not often connected.


OK, since you are making a pronoucement on elementary physics, and you
feel that only physicists are in a position to do so, I can only infer
you are a physicist. As such you are in a position to define boundary
and boundary condition. Please do so.

Before I even embark on an attempt here, I'd like to ask you why you
haven't called up a physicist at your local university physics
department and asked him or her to describe the difference. That
conversation would be much shorter and more efficient than attempting
an education on a newsgroup.
PD
.
User: "Haines Brown"

Title: Re: System boundary 09 Jun 2007 11:32:22 AM
PD <TheDraperFamily@gmail.com> writes:

On Jun 6, 3:43 pm, Haines Brown <bro...@teufel.hartford-hwp.com>
wrote:

PD <TheDraperFam...@gmail.com> writes:

Well, your babble-generator certainly starts easily with a light pull,
doesn't it? You've read too much and learned too little. It might be
useful to talk with a *physicist* to understand the difference between
a system boundary and where a boundary condition applies. Those are
two different contexts that are sometimes but not often connected.


OK, since you are making a pronoucement on elementary physics, and you
feel that only physicists are in a position to do so, I can only infer
you are a physicist. As such you are in a position to define boundary
and boundary condition. Please do so.


Before I even embark on an attempt here, I'd like to ask you why you
haven't called up a physicist at your local university physics
department and asked him or her to describe the difference. That
conversation would be much shorter and more efficient than attempting
an education on a newsgroup.

PD

Apparently I sent my reply to PD personally rather than to the
newsgroup.
In it I gave reasons why I did not consult with local academics,
although the suggestion is certainly a valid one.
I pointed out that I was not making pronouncements, but only offered
the "propositions" as a way to obtain enlightenment concerning them.
Although not in school, I am a student anxious to learn. Most teachers
find student questions, no matter how naive or misguided,
welcome. Most academics and experts feel they have learned much from
their students.
I believe I am correct to assume that the notion of boundary
conditions is an ambivalent one. In different sciences it is
understood in different ways.
Let me offer these quotations from a classic account:
A _specific_ boundary condition is simply a postulated event in
space and time expressed by the statement that a symbol,
representing a certain physical quantity, shall have a definite
value or set of values throughout a specified region of space within
a specified interval of time.
[re. _general_ boundary conditions]... when we come to physical
problems which involve the flow of energy across the interface of
two media ... it is necessary to postulate at such an interface a
certain continuity for the functions representing the disturbance
which is being propagated. ... We have to set up certain relations
among the physical quantities descriptive of the physical
quantities descriptive of the disturbance in the two media at the
boundary.
The first paragraph seems to refer to what we call an initial
condition, and asserts that its state can't be described without
defining its boundary. The term "postulated" seems to imply that there
cannot be a description of any state without a subjective
component. Since the first paragraph refers to isolated systems, it
may imply that any description of the state of an isolated system is
in part subjective because any observation entails a causal relation
with something in the system's environment and a reference system.
The second paragraph refers to closed systems that can exchange heat
with their environment and can involve work (I assume this means
perturbations affecting a system rather than free energy within the
system doing work on its elements). Here the existence of an
interface, still does not support a purely objective definition of
system, for the function representing conditions on either side of the
interface must have an element of continuity. For example, one might
wish to define a system as having lower entropy than its environment,
but the measurement of entropy is inherently comparative.
Not mentioned by the author quoted above is the open system. This is
due at least because the context is boundary conditions, and such an
open system has none. If there is an exchange of matter with the
system's environment, can it appear as a system? We can, for example,
identity a causal nexus and call it a system. This in fact is an old
definition. However, I suspect that this ends up merely a description,
and intuitively I suspect mere description does not amount to a system
in any meaningful sense.
Apparently we must conclude that there's no entirely objective
definition of system. However, the presence of a subjective component
does not necessarily mean there is no objective truth value in a
definition of system. My "propositions" were aimed at unpacking
(salvaging) this truth value. I did not elaborate the point, but it
seems to me that we can't define system unless it involves events
(involves causal relations), and has boundary conditions.
An isolated system is constructed, either in thought (a temporary
hypothetically isolated system) or in fact (the laboratory). There is
obviously truth value arising from the laboratory (general laws),
although arguably that value is one-sided in that the outcomes are
unequivocally determined by initial conditions, which generally is not
true of the world we know.
A closed system is also constructed by the observer. Is it true that
the only definition of such a system is its entropy relative to its
environment? What functional characteristics does the interface have
to have such that entropy is exported?
In the absence of an interface (boundary conditions), we have an open
system.
--

Haines Brown, KB1GRM


.
User: "PD"

Title: Re: System boundary 11 Jun 2007 06:06:42 AM
On Jun 9, 11:32 am, Haines Brown <bro...@teufel.hartford-hwp.com>
wrote:

PD <TheDraperFam...@gmail.com> writes:

On Jun 6, 3:43 pm, Haines Brown <bro...@teufel.hartford-hwp.com>
wrote:

PD <TheDraperFam...@gmail.com> writes:

Well, your babble-generator certainly starts easily with a light pull,
doesn't it? You've read too much and learned too little. It might be
useful to talk with a *physicist* to understand the difference between
a system boundary and where a boundary condition applies. Those are
two different contexts that are sometimes but not often connected.


OK, since you are making a pronoucement on elementary physics, and you
feel that only physicists are in a position to do so, I can only infer
you are a physicist. As such you are in a position to define boundary
and boundary condition. Please do so.


Before I even embark on an attempt here, I'd like to ask you why you
haven't called up a physicist at your local university physics
department and asked him or her to describe the difference. That
conversation would be much shorter and more efficient than attempting
an education on a newsgroup.


PD


Apparently I sent my reply to PD personally rather than to the
newsgroup.

In it I gave reasons why I did not consult with local academics,
although the suggestion is certainly a valid one.

I pointed out that I was not making pronouncements, but only offered
the "propositions" as a way to obtain enlightenment concerning them.

Although not in school, I am a student anxious to learn. Most teachers
find student questions, no matter how naive or misguided,
welcome. Most academics and experts feel they have learned much from
their students.

I believe I am correct to assume that the notion of boundary
conditions is an ambivalent one. In different sciences it is
understood in different ways.

Let me offer these quotations from a classic account:

A _specific_ boundary condition is simply a postulated event in
space and time expressed by the statement that a symbol,
representing a certain physical quantity, shall have a definite
value or set of values throughout a specified region of space within
a specified interval of time.

[re. _general_ boundary conditions]... when we come to physical
problems which involve the flow of energy across the interface of
two media ... it is necessary to postulate at such an interface a
certain continuity for the functions representing the disturbance
which is being propagated. ... We have to set up certain relations
among the physical quantities descriptive of the physical
quantities descriptive of the disturbance in the two media at the
boundary.

The first paragraph seems to refer to what we call an initial
condition, and asserts that its state can't be described without
defining its boundary. The term "postulated" seems to imply that there
cannot be a description of any state without a subjective
component. Since the first paragraph refers to isolated systems, it
may imply that any description of the state of an isolated system is
in part subjective because any observation entails a causal relation
with something in the system's environment and a reference system.

The second paragraph refers to closed systems that can exchange heat
with their environment and can involve work (I assume this means
perturbations affecting a system rather than free energy within the
system doing work on its elements). Here the existence of an
interface, still does not support a purely objective definition of
system, for the function representing conditions on either side of the
interface must have an element of continuity. For example, one might
wish to define a system as having lower entropy than its environment,
but the measurement of entropy is inherently comparative.

Not mentioned by the author quoted above is the open system. This is
due at least because the context is boundary conditions, and such an
open system has none. If there is an exchange of matter with the
system's environment, can it appear as a system? We can, for example,
identity a causal nexus and call it a system. This in fact is an old
definition. However, I suspect that this ends up merely a description,
and intuitively I suspect mere description does not amount to a system
in any meaningful sense.

Apparently we must conclude that there's no entirely objective
definition of system. However, the presence of a subjective component
does not necessarily mean there is no objective truth value in a
definition of system. My "propositions" were aimed at unpacking
(salvaging) this truth value. I did not elaborate the point, but it
seems to me that we can't define system unless it involves events
(involves causal relations), and has boundary conditions.

An isolated system is constructed, either in thought (a temporary
hypothetically isolated system) or in fact (the laboratory). There is
obviously truth value arising from the laboratory (general laws),
although arguably that value is one-sided in that the outcomes are
unequivocally determined by initial conditions, which generally is not
true of the world we know.

A closed system is also constructed by the observer. Is it true that
the only definition of such a system is its entropy relative to its
environment? What functional characteristics does the interface have
to have such that entropy is exported?

In the absence of an interface (boundary conditions), we have an open
system.

I will reiterate my previous suggestion that, since you seem to
readily entertain free interpretations of terms like "boundary
conditions" and "system boundaries" and do not have sufficient
information to constrain the meanings of those terms to their intended
scopes, it may be better to exercise this semantic pushing against
someone who can, for an hour or so, repeatedly say, "Well, no, it
doesn't mean that either. What it means, again, is..."
However, doing it on a newsgroup is is too inefficient a mechanism to
warrant pursuing it further here.
PD
.
User: "Haines Brown"

Title: Re: System boundary 11 Jun 2007 04:19:43 PM
Apparently my ignorance is too profound to invite discussion. I find
this attitude to be unfortunate. I have contact with people from all
walks of life and would never cut someone off because they were not up
to the level of my lofty sophistication ;-). I'm sorry that
participants in the discussion (and some other threads I've followed)
are not more self-assured and able to adjust to different intellectual
levels and contexts. It's a good thing they don't have to teach for a
living.
It was recommended I consult with local academics, as if I were asking
for information rather than for an exploratory dialog. I am acquainted
with a couple local physicists and know they are not particularly
self-aware when it comes to the philosophical implications of their
field. If the case were otherwise, I'd already have pounded at their
door.
It was recommended I read up on the thermodynamic aspect of physical
chemistry. It has been over fifty years since I've taken a physical
chemistry (1954, M.I.T.), and unfortunately did not keep the
textbook. But I will take the advice and re-study the matter. It was
recommended I turn to de Paula and Atkins' _Physical Chemistry_, but
opinions on this book are very mixed, and the overall attitude toward
it is that it is mediocre. It is faulted in particular for its lack of
explanations. Since this is what I was looking for, I ordered another
book that is rated much higher.
--

Haines Brown, KB1GRM


.
User: "PD"

Title: Re: System boundary 11 Jun 2007 11:52:39 PM
On Jun 11, 4:19 pm, Haines Brown <bro...@teufel.hartford-hwp.com>
wrote:

Apparently my ignorance is too profound to invite discussion.

That's more or less correct. At least for discussion here.

I find
this attitude to be unfortunate. I have contact with people from all
walks of life and would never cut someone off because they were not up
to the level of my lofty sophistication ;-).

That's not the issue. It isn't about cutting you off. It's about
choosing the venue. You chose to ask the question, which was based on
a very poor understanding of some basic terms, on usenet. There are
some questions which are well suited for usenet. There are some
misconceptions which are appropriately addressed on usenet. This post
was not one of them. In such a case, it is recommended that you do
find the answer and start a proper discussion, but not in the venue of
sci.physics.

I'm sorry that
participants in the discussion (and some other threads I've followed)
are not more self-assured and able to adjust to different intellectual
levels and contexts. It's a good thing they don't have to teach for a
living.

Some of them do, and it is precisely this background that gives them
the experience to know when it is better to recommend tools other than
usenet.


It was recommended I consult with local academics, as if I were asking
for information rather than for an exploratory dialog. I am acquainted
with a couple local physicists and know they are not particularly
self-aware when it comes to the philosophical implications of their
field.

Are you quite sure of that? You've already said that you haven't
pounded on their door. Have you even tried to engage them?

If the case were otherwise, I'd already have pounded at their
door.

It was recommended I read up on the thermodynamic aspect of physical
chemistry. It has been over fifty years since I've taken a physical
chemistry (1954, M.I.T.),

I guessed as much.

and unfortunately did not keep the
textbook. But I will take the advice and re-study the matter. It was
recommended I turn to de Paula and Atkins' _Physical Chemistry_, but
opinions on this book are very mixed, and the overall attitude toward
it is that it is mediocre. It is faulted in particular for its lack of
explanations. Since this is what I was looking for, I ordered another
book that is rated much higher.

If you'd like an alternate recommendation, I suggest Lionel Raff's
book. The ISBN-13 is 9780130278050, and I believe the publisher is
Prentice Hall. If you buy the textbook, you may even be able to elicit
a comment directly from him.
PD
.


User: "Haines Brown"

Title: Re: System boundary 11 Jun 2007 06:59:58 AM
PD <TheDraperFamily@gmail.com> writes:

On Jun 9, 11:32 am, Haines Brown <bro...@teufel.hartford-hwp.com>
wrote:
I will reiterate my previous suggestion that, since you seem to
readily entertain free interpretations of terms like "boundary
conditions" and "system boundaries" and do not have sufficient
information to constrain the meanings of those terms to their intended
scopes, it may be better to exercise this semantic pushing against
someone who can, for an hour or so, repeatedly say, "Well, no, it
doesn't mean that either. What it means, again, is..."

However, doing it on a newsgroup is is too inefficient a mechanism to
warrant pursuing it further here.

PD

Understood. You can not, or do not wish to, define "boundary
conditions". Also, you do not choose to correct my take on the
quotation from a standard work that defines boundary conditions in two
senses, one for isolated systems and one for closed systems.
Since I have no ready access to academics with whom I might discuss
the matter at length, please direct me to the appropriate
literature. Something beyond merely the effect of boundary conditions
in particular situations, but a definition of boundary conditions per
se, their effect in general upon systems.
--

Haines Brown, KB1GRM


.
User: "The_Man"

Title: Re: System boundary 11 Jun 2007 07:23:59 AM
On Jun 11, 7:59 am, Haines Brown <bro...@teufel.hartford-hwp.com>
wrote:

PD <TheDraperFam...@gmail.com> writes:

On Jun 9, 11:32 am, Haines Brown <bro...@teufel.hartford-hwp.com>
wrote:
I will reiterate my previous suggestion that, since you seem to
readily entertain free interpretations of terms like "boundary
conditions" and "system boundaries" and do not have sufficient
information to constrain the meanings of those terms to their intended
scopes, it may be better to exercise this semantic pushing against
someone who can, for an hour or so, repeatedly say, "Well, no, it
doesn't mean that either. What it means, again, is..."


However, doing it on a newsgroup is is too inefficient a mechanism to
warrant pursuing it further here.


PD


Understood. You can not, or do not wish to, define "boundary
conditions". Also, you do not choose to correct my take on the
quotation from a standard work that defines boundary conditions in two
senses, one for isolated systems and one for closed systems.

PD has given you a concise, accurate, and consistent answer. You seem
more interested in philosophical musing than learning anything


Since I have no ready access to academics with whom I might discuss
the matter at length,

You don't own a telephone?
There are no colleges/Universities in your area?
You don't have an email account?
You don't have any bookstores or libraries?

please direct me to the appropriate
literature. Something beyond merely the effect of boundary conditions
in particular situations, but a definition of boundary conditions per
se, their effect in general upon systems.

You are still very confused; boundaries and boundary conditions are
not necessarily the same thing.
Get a textbook like Atkins "Physical Chemistry". Start reading the
sections on thermodynamics. Do the problems at the end of each
chapter. The answers are in the back of the book so you'll know if you
got the right answer. There is an excellent solutions manual as a
companion for the text. Keep doing the probelms until you can answer
all of them correctly.
Then go to the chapters on statistical thermodynamics. Do the same.
When you have finished, come back and perhaps we'll entertain your
philosophical musings at that point, when you actually know something.


--

Haines Brown, KB1GRM

.





User: ""

Title: Re: System boundary 12 Jun 2007 01:03:10 AM
On Jun 7, 6:43 am, Haines Brown <bro...@teufel.hartford-hwp.com>
wrote:

PD <TheDraperFam...@gmail.com> writes:

Well, your babble-generator certainly starts easily with a light pull,
doesn't it? You've read too much and learned too little. It might be
useful to talk with a *physicist* to understand the difference between
a system boundary and where a boundary condition applies. Those are
two different contexts that are sometimes but not often connected.


OK, since you are making a pronoucement on elementary physics, and you
feel that only physicists are in a position to do so, I can only infer
you are a physicist. As such you are in a position to define boundary
and boundary condition. Please do so.

You judge a plant by its fruit. How can anyone that did not
immediately realize the Apollo moon landings were faked be a
physicist?
.
User: "PD"

Title: Re: System boundary 12 Jun 2007 05:31:56 AM
On Jun 12, 1:03 am,
wrote:

On Jun 7, 6:43 am, Haines Brown <bro...@teufel.hartford-hwp.com>
wrote:

PD <TheDraperFam...@gmail.com> writes:

Well, your babble-generator certainly starts easily with a light pull,
doesn't it? You've read too much and learned too little. It might be
useful to talk with a *physicist* to understand the difference between
a system boundary and where a boundary condition applies. Those are
two different contexts that are sometimes but not often connected.


OK, since you are making a pronoucement on elementary physics, and you
feel that only physicists are in a position to do so, I can only infer
you are a physicist. As such you are in a position to define boundary
and boundary condition. Please do so.


You judge a plant by its fruit. How can anyone that did not
immediately realize the Apollo moon landings were faked be a
physicist?

How can anyone that immediately snaps up any available conspiracy
theory as unblemished truth be a physicist? Oh, never mind. You're
not.
You do realize, don't you, that SARS and avian flue are a fiction, the
result of economic war between Western nations and China?
You do realize, don't you, that the WWW was an NSA project fronted by
government-paid physicists to complete a vast surveillance network on
citizens worldwide? Everything you type is recorded forever, and where
you're sitting tracked moment by moment, through computers, through
cell phones, through any device that touches the internet. Only third-
world citizens who have never been on the WWW are safe.
PD
PD
.
User: ""

Title: Re: System boundary 12 Jun 2007 08:44:27 AM
On Jun 12, 8:31 pm, PD <TheDraperFam...@gmail.com> wrote:

You do realize, don't you, that SARS and avian flue are a fiction, the
result of economic war between Western nations and China?

Yes, that is the impression I get about SARS and Avian flu - the
impression of a hoax. Is "bird flu", a theoretical virus, a news item
worthy of peddling across the global media for years on end? Is "bird
flu" really so dangerous that governments need to stockpile an
overpriced drug that does not cure a virus THAT DOES NOT EVEN EXIST?
Compare that with the coverage of a real ecological disaster which
could wipe out 90% of humans in 4 years: http://www.cosmosmagazine.com/node/1087

You do realize, don't you, that the WWW was an NSA project fronted by
government-paid physicists to complete a vast surveillance network on
citizens worldwide? Everything you type is recorded forever, and where
you're sitting tracked moment by moment, through computers, through
cell phones, through any device that touches the internet. Only third-
world citizens who have never been on the WWW are safe.

You shouldn't worry too much. People like me already understand that
people like you can't deal with their problems. We accept that we must
deal with them for you - it's the burden the intelligent few must
carry (perhaps even the source of this conspiracy?)
.
User: "PD"

Title: Re: System boundary 12 Jun 2007 09:05:32 AM
On Jun 12, 8:44 am,
wrote:

On Jun 12, 8:31 pm, PD <TheDraperFam...@gmail.com> wrote:

You do realize, don't you, that SARS and avian flue are a fiction, the
result of economic war between Western nations and China?


Yes, that is the impression I get about SARS and Avian flu - the
impression of a hoax.

Of course you do. That's why I made that up, to chuck another stick of
wood on your bonfire of paranoia.

Is "bird flu", a theoretical virus, a news item
worthy of peddling across the global media for years on end? Is "bird
flu" really so dangerous that governments need to stockpile an
overpriced drug that does not cure a virus THAT DOES NOT EVEN EXIST?

Compare that with the coverage of a real ecological disaster which
could wipe out 90% of humans in 4 years:http://www.cosmosmagazine.com/node/1087

You do realize, don't you, that the WWW was an NSA project fronted by
government-paid physicists to complete a vast surveillance network on
citizens worldwide? Everything you type is recorded forever, and where
you're sitting tracked moment by moment, through computers, through
cell phones, through any device that touches the internet. Only third-
world citizens who have never been on the WWW are safe.


You shouldn't worry too much. People like me already understand that
people like you can't deal with their problems. We accept that we must
deal with them for you - it's the burden the intelligent few must
carry (perhaps even the source of this conspiracy?)

Ah, thank you so much, the Keeper of the Inside Truth, and the
Protector of Sheeple, ye of the Tin Foil Hat, armed with the X-Ray
Glasses of Superior Intellect and the Lance of the Internet.
Tell you what. Why don't you just use your astute intellect to
*remove* the perpetrators of the conspiracy rather than just whining
about them? Clearly, if you are the one with superior intelligence,
then simply complaining about the conspiracy to an audience with
inferior intellect will get nothing accomplished. After all, the
sheeple are too dim-witted to even see the problem, let alone fix it.
It is up to you to fix it, with direct and personal action. You are
the only one that sees the problem, therefore you are the only one
smart enough to devise a plan to solve the problem, and the only one
clear-headed enough to execute that plan. You are doing your
intelligence a disservice if you do not put your thinking into
concrete results. Get to it. I hope to see your name in the news soon.
I don't see how you could live with yourself if you didn't. You have a
responsibility, you know. A profound responsibility.
PD
.








User: "Puppet_Sock"

Title: Re: System boundary 05 Jun 2007 12:24:26 PM
On Jun 5, 1:01 pm, Haines Brown <bro...@teufel.hartford-hwp.com>
wrote:

I'm trying to grasp the broader ontological implications of a system
boundary as described in physics. I'd appreciate knowing if you think
any of the following propositions are incorrect or inaccurate.

[snip]
I think all your statements are word salad and can, at best,
produce nothing but confusion. The mere fact that your *use*
the word "ontological" indicates that you are in the wrong
news group.
Socks
.
User: "Haines Brown"

Title: Re: System boundary 05 Jun 2007 02:49:22 PM
Puppet_Sock <puppet_sock@hotmail.com> writes:

I think all your statements are word salad and can, at best, produce
nothing but confusion. The mere fact that your *use* the word
"ontological" indicates that you are in the wrong news group.
Socks

I sincerely regret that my little "propositions" gave cause for dismay
on your part. However, I'm left uncertain as to just to what you
object.
The word "ontology" is surely conventional in the philosophy of
science. Am I correct to infer from your objection to it that you
dismiss any discussion of the philosophical implications or
underpinnings of physics? I know there are some who feel that way, but
there are many others who do not.
As for this being the wrong newsgroup, my impression of it is that
discussions here have not excluded the philosophical implications of
physics. I see nothing in the description of the group that implies
the philosophical implications are irrelevant. Correct me if I'm
wrong.
Your phrase "word salad" leaves me uncertain. Would you do me a favor
and explain just what you meant by it? I tried to use terms that are
conventional in physics and to employ them logically. Just to
illustrate, here again is my first "proposition":
1. The notion of "systemness" implies the existence of a boundary
between the system and its environment. In the absence of a
boundary, there is no system and hence no definition of system
state. Boundary is what makes the system an entity that has
properties.
This statement I thought was entirely conventional! It was meant
primarily to set the framework for the following propositions. The
term "system" is much debated, but as far as I know, no one has
doubted that it is an important concept in physics, although a
challenge to define. Likewise for the term boundary. The term "entity"
is also much discussed, but I assumed in this newsgroup that folks
would understand its meaning. The last two sentences I assumed were
quite transparent. So where's the beef?
Just to illustrate how conventional this first point is, let me refer
to that great classic, Foundations of Physics, by Robert Bruce Lindsay
and Henry Margenau (1936), particularly section 1.9, which takes a
position very similar to my own, although in a more developed way. If
such a standard physics text makes a point similar to my own, what is
there to object to in my own statement?
In my point 4 I do become a little adventurous, for here I bring in
the philosophy of scientific realism. True, that has been a minority
position over the years, but it has been winning increasing attention
of late. Point 5 drags in the issue of probabilistic causality,
another contentious subject, but by no means unconventional. My
propositions 6 and 7 merely sought to clarify what I assumed were
conventional points.
Surely there are participants here who take some interest in the
philosophical implications of their field, but even if not, surely we
all are concerned for precise definitions of the terms we use, and
that was what my propositions aimed at. I really would like to have
someone identify my errors and points of confusion. I asked for help,
and hopefully someone will be kind enough to offer it and not see my
question as a confrontation.
--

Haines Brown, KB1GRM


.
User: "Puppet_Sock"

Title: Re: System boundary 05 Jun 2007 03:58:34 PM
On Jun 5, 3:49 pm, Haines Brown <bro...@teufel.hartford-hwp.com>
wrote:
[snip]

Your phrase "word salad" leaves me uncertain.

You were uncertain long before I used the phrase. There
is little that can be done to rescue you.
Try a forum with "philosophy" in the name. They like word salad.
Socks
.




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