Urea



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Topic: Science > Physics
User: "Gregory L. Hansen"
Date: 14 Mar 2005 07:53:18 PM
Object: Urea
I was going through some paperwork and found something I must have
scribbled into a notebook fifteen years ago. It's a little crude, but
sing to the tune of "Maria".
Urea
I think that I've just made urea.
Not from my body waste,
But in the lab from bas-
ic things.
Urea.
Suddenly the chemistry of life is laid out for me.
Urea.
My lab has the smell of urea!
They said it can't be done,
A chemical that comes
from life.
Urea!
--
"A good plan executed right now is far better than a perfect plan
executed next week."
-Gen. George S. Patton
.

User: "Uncle Al"

Title: Re: Urea 14 Mar 2005 08:34:19 PM
"Gregory L. Hansen" wrote:


I was going through some paperwork and found something I must have
scribbled into a notebook fifteen years ago. It's a little crude, but
sing to the tune of "Maria".

Urea
I think that I've just made urea.
Not from my body waste,
But in the lab from bas-
ic things.
Urea.
Suddenly the chemistry of life is laid out for me.
Urea.
My lab has the smell of urea!
They said it can't be done,
A chemical that comes
from life.
Urea!

"Romeo and Juliet" adapted to Caucasians browned to Puerto Ricans.
Amazing.
Urea is not an organic chemical - it contains no C-C or C-H bond. It
is odorless as the white solid or in colorless solution. Wöhler’s
(Woehler's) in vitro synthesis of urea from ammonium cyanate was not a
valid counterdemonstration of Vital Force doctrine.
The first apparent organic synthesis from strict inorganics might have
been croconic acid (as the salt) or leuconic acid
(cyclopentanepentanone tetra- or pentahydrate) from carbon monoxide
(possibly wet) passed over glowing hot charcoal or coke doped with
alkali.
Chemistry - A European Journal 8(8) Pages 1804 (2002)
--
Uncle Al
http://www.mazepath.com/uncleal/
(Toxic URL! Unsafe for children and most mammals)
http://www.mazepath.com/uncleal/qz.pdf
.
User: "Ken S. Tucker"

Title: Re: Urea 14 Mar 2005 08:50:23 PM
Now that you mention it....
As brat's we'd put a inch or so of pee in a
test tube then boil, it would bubble then
explode.
It did that repeatedly, never did figure out
why. Anyway after a few times of getting
showered with pee when it hit the ceiling
we stopped doing that.
We we're fast learners!
Ken
.
User: "tadchem"

Title: Re: Urea 15 Mar 2005 01:20:07 PM
Fast learners would have stopped after the FIRST time.
Smart students would have prodded *someone else* to try it first.
Tom Davidson
Richmond, VA
.
User: "Ken S. Tucker"

Title: Re: Urea 15 Mar 2005 04:13:04 PM
tadchem wrote:

Fast learners would have stopped after the FIRST time.
Smart students would have prodded *someone else* to try it first.
Tom Davidson
Richmond, VA

LOL, you may remember those massive chemistry
sets, that were sold in the 60's, well to the
chagrin of me mom, we kids decided to unify a
lab in her basement, (dad was ok with it).
We collected anything we could get.
Anyway, why does pee explode?
Ken
.
User: "FrediFizzx"

Title: Re: Urea 15 Mar 2005 07:17:12 PM
"Ken S. Tucker" <dynamics@vianet.on.ca> wrote in message
news:1110924784.277922.121000@l41g2000cwc.googlegroups.com...
|
| tadchem wrote:
| > Fast learners would have stopped after the FIRST time.
| > Smart students would have prodded *someone else* to try it first.
| > Tom Davidson
| > Richmond, VA
|
| LOL, you may remember those massive chemistry
| sets, that were sold in the 60's, well to the
| chagrin of me mom, we kids decided to unify a
| lab in her basement, (dad was ok with it).
| We collected anything we could get.
|
| Anyway, why does pee explode?
ROTHFLMAO
I think you need to start a new thread with that question.
FrediFizzx
.
User: "Gregory L. Hansen"

Title: Re: Urea 15 Mar 2005 07:26:47 PM
In article <39pfheF65onsaU1@individual.net>,
FrediFizzx <fredifizzx@hotmail.com> wrote:

"Ken S. Tucker" <dynamics@vianet.on.ca> wrote in message
news:1110924784.277922.121000@l41g2000cwc.googlegroups.com...
|
| tadchem wrote:
| > Fast learners would have stopped after the FIRST time.
| > Smart students would have prodded *someone else* to try it first.
| > Tom Davidson
| > Richmond, VA
|
| LOL, you may remember those massive chemistry
| sets, that were sold in the 60's, well to the
| chagrin of me mom, we kids decided to unify a
| lab in her basement, (dad was ok with it).
| We collected anything we could get.
|
| Anyway, why does pee explode?

ROTHFLMAO

I think you need to start a new thread with that question.

I trust the experiment had been run with water and the same effect wasn't
found?
--
"Then they placed the ark of the Lord on the cart; along with the box
containing the golden mice and the images of the hemorrhoids."
-- 1 Samuel 6:11
.
User: "Ken S. Tucker"

Title: Re: Urea 18 Mar 2005 03:47:43 PM
Gregory L. Hansen wrote:

In article <39pfheF65onsaU1@individual.net>,
FrediFizzx <fredifizzx@hotmail.com> wrote:

"Ken S. Tucker" <dynamics@vianet.on.ca> wrote in message
news:1110924784.277922.121000@l41g2000cwc.googlegroups.com...
|
| tadchem wrote:
| > Fast learners would have stopped after the FIRST time.
| > Smart students would have prodded *someone else* to try it

first.

| > Tom Davidson
| > Richmond, VA
|
| LOL, you may remember those massive chemistry
| sets, that were sold in the 60's, well to the
| chagrin of me mom, we kids decided to unify a
| lab in her basement, (dad was ok with it).
| We collected anything we could get.
| Anyway, why does pee explode?
ROTHFLMAO
I think you need to start a new thread with that question.

Yeah, in alt.loonychemistry :-)

I trust the experiment had been run with water and the same effect

wasn't

found?

Of course...
IIRC, (40 years ago) we used a 1 inch x 8 inch
test tube and a candle under the bottom, held
it with a clothes peg.
It would boil up 2-3 times then boom, splat,
I felt a noticable recoil.
A few years later a China man who lived there
as a kid in the 30's explained how he and his
friends would use a spoon to scrape off deposits
from urinals and toilets to make fireworks.
Ken
.
User: "Gregory L. Hansen"

Title: Re: Urea 18 Mar 2005 04:12:07 PM
In article <1111182463.354684.316710@z14g2000cwz.googlegroups.com>,
Ken S. Tucker <dynamics@vianet.on.ca> wrote:


Gregory L. Hansen wrote:

In article <39pfheF65onsaU1@individual.net>,
FrediFizzx <fredifizzx@hotmail.com> wrote:
I trust the experiment had been run with water and the same effect

wasn't

found?


Of course...
IIRC, (40 years ago) we used a 1 inch x 8 inch
test tube and a candle under the bottom, held
it with a clothes peg.
It would boil up 2-3 times then boom, splat,
I felt a noticable recoil.
A few years later a China man who lived there
as a kid in the 30's explained how he and his
friends would use a spoon to scrape off deposits
from urinals and toilets to make fireworks.

I'm almost tempted to try that myself, if it weren't so gross.
But it seems like it would be easier to just pee in a beaker and boil it
down. Still gross.
--
"The preferred method of entering a building is to use a tank main gun
round, direct fire artillery round, or TOW, Dragon, or Hellfire missile to
clear the first room." -- THE RANGER HANDBOOK U.S. Army, 1992
.
User: ""

Title: Re: Urea 18 Mar 2005 04:21:21 PM
Gregory L. Hansen <glhansen@steel.ucs.indiana.edu> wrote:

In article <1111182463.354684.316710@z14g2000cwz.googlegroups.com>,
Ken S. Tucker <dynamics@vianet.on.ca> wrote:


Gregory L. Hansen wrote:

In article <39pfheF65onsaU1@individual.net>,
FrediFizzx <fredifizzx@hotmail.com> wrote:
I trust the experiment had been run with water and the same effect

wasn't

found?


Of course...
IIRC, (40 years ago) we used a 1 inch x 8 inch
test tube and a candle under the bottom, held
it with a clothes peg.
It would boil up 2-3 times then boom, splat,
I felt a noticable recoil.
A few years later a China man who lived there
as a kid in the 30's explained how he and his
friends would use a spoon to scrape off deposits
from urinals and toilets to make fireworks.

I'm almost tempted to try that myself, if it weren't so gross.
But it seems like it would be easier to just pee in a beaker and boil it
down. Still gross.
--
"The preferred method of entering a building is to use a tank main gun
round, direct fire artillery round, or TOW, Dragon, or Hellfire missile to
clear the first room." -- THE RANGER HANDBOOK U.S. Army, 1992

It would be easier and non-gross to go to a nursery and buy a bag.
--
Jim Pennino
Remove -spam-sux to reply.
.
User: "Ken S. Tucker"

Title: Re: Urea 18 Mar 2005 05:13:34 PM
wrote:

Gregory L. Hansen <glhansen@steel.ucs.indiana.edu> wrote:

In article <1111182463.354684.316710@z14g2000cwz.googlegroups.com>,
Ken S. Tucker <dynamics@vianet.on.ca> wrote:


Gregory L. Hansen wrote:

In article <39pfheF65onsaU1@individual.net>,
FrediFizzx <fredifizzx@hotmail.com> wrote:


I trust the experiment had been run with water and the same

effect

wasn't

found?


Of course...
IIRC, (40 years ago) we used a 1 inch x 8 inch
test tube and a candle under the bottom, held
it with a clothes peg.
It would boil up 2-3 times then boom, splat,
I felt a noticable recoil.
A few years later a China man who lived there
as a kid in the 30's explained how he and his
friends would use a spoon to scrape off deposits
from urinals and toilets to make fireworks.


I'm almost tempted to try that myself, if it weren't so gross.


But it seems like it would be easier to just pee in a beaker and

boil it

down. Still gross.

It would be easier and non-gross to go to a nursery and buy a bag.

--
Jim Pennino

I'm guessing here.
The ammonium nitrate may have mixed with the
paraffin fumes from the candle, McVeigh style,
or
the explosive is characteristic to pee.
When I brought the subject up here, I figured
lot's of kids did this experiment. As I
recall the brat motive at first was distillation,
which seems curious and benign enough.
Maybe I should order a cigar in a glass flask
from purchasing.
Ken
.
User: "Jan Panteltje"

Title: Re: Urea 19 Mar 2005 08:20:41 AM
On a sunny day (18 Mar 2005 15:13:34 -0800) it happened "Ken S. Tucker"
<dynamics@vianet.on.ca> wrote in
<1111187614.519264.120790@o13g2000cwo.googlegroups.com>:

When I brought the subject up here, I figured
lot's of kids did this experiment. As I
recall the brat motive at first was distillation,
which seems curious and benign enough.

Of cause I did the experiment, but I, being electronically
oriented, used electrolysis.
It was not the gasses that could be dangerous when ignited, but
mainly the strong neutron radiation from mine.
It set in motion this whole search for cold fusion, but this is
the first time I am revealing the real ingredient.
Copyright Jan Panteltje 2005 All Rights Reserved
.


User: "Gregory L. Hansen"

Title: Re: Urea 18 Mar 2005 07:52:41 PM
In article <d1fk91$jni$1@mail.specsol.com>, <jimp@specsol-spam-sux.com> wrote:

Gregory L. Hansen <glhansen@steel.ucs.indiana.edu> wrote:

In article <1111182463.354684.316710@z14g2000cwz.googlegroups.com>,
Ken S. Tucker <dynamics@vianet.on.ca> wrote:


Gregory L. Hansen wrote:

In article <39pfheF65onsaU1@individual.net>,
FrediFizzx <fredifizzx@hotmail.com> wrote:


I trust the experiment had been run with water and the same effect

wasn't

found?


Of course...
IIRC, (40 years ago) we used a 1 inch x 8 inch
test tube and a candle under the bottom, held
it with a clothes peg.
It would boil up 2-3 times then boom, splat,
I felt a noticable recoil.
A few years later a China man who lived there
as a kid in the 30's explained how he and his
friends would use a spoon to scrape off deposits
from urinals and toilets to make fireworks.


I'm almost tempted to try that myself, if it weren't so gross.


But it seems like it would be easier to just pee in a beaker and boil it
down. Still gross.


--
"The preferred method of entering a building is to use a tank main gun
round, direct fire artillery round, or TOW, Dragon, or Hellfire missile to
clear the first room." -- THE RANGER HANDBOOK U.S. Army, 1992


It would be easier and non-gross to go to a nursery and buy a bag.

That's true. Grown-ups can afford things like that. But there's still
something... self-reliant about home-grown explosives.
--
"Usenet is like a herd of performing elephants with diarrhea -- massive,
difficult to redirect, awe-inspiring, entertaining, and a source of
mind-boggling amounts of excrement when you least expect it. "
-- Gene Spafford, 1992
.
User: ""

Title: Re: Urea 18 Mar 2005 08:16:44 PM
Gregory L. Hansen <glhansen@steel.ucs.indiana.edu> wrote:

In article <d1fk91$jni$1@mail.specsol.com>, <jimp@specsol-spam-sux.com> wrote:

<snip>

It would be easier and non-gross to go to a nursery and buy a bag.

That's true. Grown-ups can afford things like that. But there's still
something... self-reliant about home-grown explosives.

I hear that.
I remember as a kid jumping through my butt to get the stuff to make
my own black powder when I could have easily just gone to the sporting
goods store and bought a pound can for a buck or so.
--
Jim Pennino
Remove -spam-sux to reply.
.
User: "Gregory L. Hansen"

Title: Re: Urea 18 Mar 2005 08:41:01 PM
In article <d1g22c$t5p$2@mail.specsol.com>, <jimp@specsol-spam-sux.com> wrote:

Gregory L. Hansen <glhansen@steel.ucs.indiana.edu> wrote:

In article <d1fk91$jni$1@mail.specsol.com>,

<jimp@specsol-spam-sux.com> wrote:

<snip>

It would be easier and non-gross to go to a nursery and buy a bag.


That's true. Grown-ups can afford things like that. But there's still
something... self-reliant about home-grown explosives.


I hear that.

I remember as a kid jumping through my butt to get the stuff to make
my own black powder when I could have easily just gone to the sporting
goods store and bought a pound can for a buck or so.

We used to get sulfur by going to the train tracks and throwing rocks at
the sulfer cars as they rolled past, then we picked up the chips when the
train had left. If we had thought of boiling down pee, we might have done
it.
--
"Things should be made as simple as possible -- but no simpler."
-- Albert Einstein
.










User: "Mitchell Jones"

Title: Re: Urea 17 Mar 2005 07:12:14 PM
In article <1110855023.315767.122470@f14g2000cwb.googlegroups.com>,
"Ken S. Tucker" <dynamics@vianet.on.ca> wrote:

Now that you mention it....

As brat's we'd put a inch or so of pee in a
test tube then boil, it would bubble then
explode.
It did that repeatedly, never did figure out
why. Anyway after a few times of getting
showered with pee when it hit the ceiling
we stopped doing that.
We we're fast learners!
Ken

***{Exploding pee? That's a new one on me! Let's see, the first thing
that comes to mind is:
4CO(NH2)2 + 5O2 --> 4NH3 + 4NO + 4CO2 + 2H20
It balances, but is it a real possibility? And is it, as seems likely,
exothermic? I suppose I could plug in the appropriate heats of formation
and muck around until I had an answer, but it looks pretty tedious and I
don't really have time to mess with it. Besides I'm sure you chem guys
have programs to do that sort of thing. So what about it? Does pee
explode, or not? And if it does, does the above reaction have anything
to do with it?
Enquiring minds want to know!
--Mitchell Jones}***
.
User: "The Ghost In The Machine"

Title: Re: Urea 19 Mar 2005 01:00:02 AM
In sci.physics, Mitchell Jones
<mjones@21cenlogic.com>
wrote
on 17 Mar 2005 20:12:14 EST
<mjones-4213E0.19140317032005@spectator.sj.sys.us.xo.net>:

In article <1110855023.315767.122470@f14g2000cwb.googlegroups.com>,
"Ken S. Tucker" <dynamics@vianet.on.ca> wrote:

Now that you mention it....

As brat's we'd put a inch or so of pee in a
test tube then boil, it would bubble then
explode.
It did that repeatedly, never did figure out
why. Anyway after a few times of getting
showered with pee when it hit the ceiling
we stopped doing that.
We we're fast learners!
Ken


***{Exploding pee? That's a new one on me! Let's see, the first thing
that comes to mind is:

4CO(NH2)2 + 5O2 --> 4NH3 + 4NO + 4CO2 + 2H20

It balances, but is it a real possibility? And is it, as seems likely,
exothermic? I suppose I could plug in the appropriate heats of formation
and muck around until I had an answer, but it looks pretty tedious and I
don't really have time to mess with it. Besides I'm sure you chem guys
have programs to do that sort of thing. So what about it? Does pee
explode, or not? And if it does, does the above reaction have anything
to do with it?

Enquiring minds want to know!

Well, let's tote up the bonds; it's not quite as tedious
as you might think. For quick reference:
http://www.chemistrycoach.com/table_of_bond_enthalpies.htm
4CO(NH2)2 + 5O2 --> 4NH3 + 4NO + 4CO2 + 2H20
4 C=O 5 O=O 12 N-H ?? 8 C=O 4 H-O
8 C-N
16 N-H
On the left side:
4 C=O = 127*4
8 C-N = 72*8
16 N-H = 110 * 16
5 O=O = 119 * 5
Total: 3439 kcal/mole
Right side has the NO problem; for now, we'll ignore it.
12 N-H = 110 * 12
8 C=O = 127*4
4 H-O = 111 * 4
Total is 2272 kcal/mole, without the N-O bond. If we assume
the N-O bond is about 200 (which is ridiculously high),
we get 3072 kcal/mole -- which still indicates a highly endothermic
reaction, as contrasted to the burning of methane gas:
CH4 + 2O2 => CO2 + 2H2O
4 C-H 2 O=O 2 C=O 4 H-O
(99 * 4) + (119 * 2) = 634
(127 * 2) + (111 * 4) = 698
The calculated energy for *this* reaction
is approximately +64 kcal/mole of methane.
Of course, most pee has quite a bit of water in it; that might
be a factor. Funny things happen with water; ethyl alcohol
in particular cannot be entirely distilled by boiling alone,
for example.
Then again, I'm far from expert in this stuff.


--Mitchell Jones}***

--
#191,

It's still legal to go .sigless.
.

User: "John Park"

Title: Re: Urea 18 Mar 2005 11:52:26 PM
Mitchell Jones (mjones@21cenlogic.com) writes:
[...]


***{Exploding pee? That's a new one on me! Let's see, the first thing
that comes to mind is:

4CO(NH2)2 + 5O2 --> 4NH3 + 4NO + 4CO2 + 2H20

[...]
I'd have guessed
CO(NH2)2 + H2O --> CO2 + 2NH3.
Much simpler. In hot water the carbon dioxide and probably the ammonia would
produce a fizz. But I haven't checked out the chemistry in detail either.
--John Park
.

User: "Uncle Al"

Title: Re: Urea 17 Mar 2005 07:21:43 PM
Mitchell Jones wrote:


In article <1110855023.315767.122470@f14g2000cwb.googlegroups.com>,
"Ken S. Tucker" <dynamics@vianet.on.ca> wrote:

Now that you mention it....

As brat's we'd put a inch or so of pee in a
test tube then boil, it would bubble then
explode.
It did that repeatedly, never did figure out
why. Anyway after a few times of getting
showered with pee when it hit the ceiling
we stopped doing that.
We we're fast learners!
Ken


***{Exploding pee? That's a new one on me! Let's see, the first thing
that comes to mind is:

4CO(NH2)2 + 5O2 --> 4NH3 + 4NO + 4CO2 + 2H20

It balances, but is it a real possibility? And is it, as seems likely,
exothermic? I suppose I could plug in the appropriate heats of formation
and muck around until I had an answer, but it looks pretty tedious and I
don't really have time to mess with it. Besides I'm sure you chem guys
have programs to do that sort of thing. So what about it? Does pee
explode, or not? And if it does, does the above reaction have anything
to do with it?

Enquiring minds want to know!

If you don't put a boiling chip in a test tube of liquid and are so
stupid as to heat the bottom not the side, it bumps. Coarse (1/8 -
1/4") carborundum abrasive is a fantastic and cheap boiling chip. It
is inert to just about everything including temperature and can easily
be seen against your (presumbly) white product. One bag supplies the
whole lab.
--
Uncle Al
http://www.mazepath.com/uncleal/
(Toxic URL! Unsafe for children and most mammals)
http://www.mazepath.com/uncleal/qz.pdf
.
User: "Mitchell Jones"

Title: Re: Urea 18 Mar 2005 11:07:59 AM
In article <423A2D27.1C423B4B@hate.spam.net>,
Uncle Al <UncleAl0@hate.spam.net> wrote:

Mitchell Jones wrote:


In article <1110855023.315767.122470@f14g2000cwb.googlegroups.com>,
"Ken S. Tucker" <dynamics@vianet.on.ca> wrote:

Now that you mention it....

As brat's we'd put a inch or so of pee in a
test tube then boil, it would bubble then
explode.
It did that repeatedly, never did figure out
why. Anyway after a few times of getting
showered with pee when it hit the ceiling
we stopped doing that.
We we're fast learners!
Ken


***{Exploding pee? That's a new one on me! Let's see, the first thing
that comes to mind is:

4CO(NH2)2 + 5O2 --> 4NH3 + 4NO + 4CO2 + 2H20

It balances, but is it a real possibility? And is it, as seems likely,
exothermic? I suppose I could plug in the appropriate heats of formation
and muck around until I had an answer, but it looks pretty tedious and I
don't really have time to mess with it. Besides I'm sure you chem guys
have programs to do that sort of thing. So what about it? Does pee
explode, or not? And if it does, does the above reaction have anything
to do with it?

Enquiring minds want to know!


If you don't put a boiling chip in a test tube of liquid and are so
stupid as to heat the bottom not the side, it bumps.

***{Meaning, I suppose, that some of the water flashes to steam at the
bottom, and spits the rest of the liquid out the top of the tube? And
the chip is there, I guess, to acquire the kinetic energy in place of
the liquid, and then give it back via frictional losses, thereby keeping
the liquid in the tube? I guess that makes sense. --MJ}***
Coarse (1/8 -

1/4") carborundum abrasive is a fantastic and cheap boiling chip. It
is inert to just about everything including temperature and can easily
be seen against your (presumbly) white product. One bag supplies the
whole lab.

***{The new question, then, is this: if you put some pee in a test tube
with a piece of coarse carborundum abrasive and heat it with a bunsen
burner, does it explode? Me, I have lots of pee, but no test tube,
bunsen burner, or carborundum abrasive, so I guess I'll await the
results of others.
Note: these results are of significance to the teeming multitudes
confined in jails and prisons within this great country of ours, for if
pee does in fact explode, then they have munitions which the prison
administrators cannot, even in principle, take away. Indeed, mix pee
with a good oxidizer (blood, for example), soak into a roll of toilet
paper, dry thoroughly, and apply heat--and what happens? A bad smell is
of course guaranteed, but are there accompanying pyrotechnics?
--Mitchell Jones}***
.
User: ""

Title: Re: Urea 18 Mar 2005 11:33:57 AM
Mitchell Jones <mjones@21cenlogic.com> wrote:
<snip>

***{Meaning, I suppose, that some of the water flashes to steam at the
bottom, and spits the rest of the liquid out the top of the tube? And
the chip is there, I guess, to acquire the kinetic energy in place of
the liquid, and then give it back via frictional losses, thereby keeping
the liquid in the tube? I guess that makes sense. --MJ}***

No, it provides nucleation points which causes bubbles to form.
It is the same physics that causes a clean cup of water heated in a
microwave to boil over when you dump the instant coffee in it.
<snip remaining>
--
Jim Pennino
Remove -spam-sux to reply.
.
User: "Mitchell Jones"

Title: Re: Urea 18 Mar 2005 02:11:09 PM
In article <d1f3e5$slg$1@mail.specsol.com>,

wrote:

Mitchell Jones <mjones@21cenlogic.com> wrote:

<snip>

***{Meaning, I suppose, that some of the water flashes to steam at the
bottom, and spits the rest of the liquid out the top of the tube? And
the chip is there, I guess, to acquire the kinetic energy in place of
the liquid, and then give it back via frictional losses, thereby keeping
the liquid in the tube? I guess that makes sense. --MJ}***


No, it provides nucleation points which causes bubbles to form.

***{The bubbles, presumably, would be steam. Steam does not form due to
"nucleation points." It forms because that portion of the water received
its heat of vaporization. After a bubble forms, of course, the point in
question can be described as a "nucleation point," but that does not
mean nucleation is the *cause* of the formation of the bubble. It is, in
fact, just another way of saying a bubble formed. The cause is the fact
that the water at that location got the heat it needed to flash to
steam. That would be the water in contact with the wall of the test tube
adjacent to the point where the heat was applied. The advantage of
applying the heat from the side would be that if a volume element
flashed to steam at that location, it would mainly thrust the liquid in
the tube horizontally, toward the opposite wall, rather than vertically,
and out of the test tube. --MJ}***

It is the same physics that causes a clean cup of water heated in a
microwave to boil over when you dump the instant coffee in it.

***{Instant coffee contains lots of volatile oils that vaporize at
temperatures well below the boiling point of water. The foaming that you
see occurs despite the fact that none of the water is flashing to steam.
Each point where a bubble appears, of course, is a "nucleation point,"
because that's just another way of saying a bubble appeared there. But,
again, it is the fact that enough heat was delivered to vaporize the
oil, which is the cause of the bubble formation at that location. There
are, of course, "condensation nuclei"--i.e., particles which facilitate
condensation--but a parallel notion of "vaporization nuclei" would be a
stretch under the best circumstances, and it certainly does not apply to
the situation we are discussing. --MJ}***

<snip remaining>

.
User: "Gregory L. Hansen"

Title: Re: Urea 18 Mar 2005 03:24:10 PM
In article <mjones-E4635D.14125618032005@spectator.sj.sys.us.xo.net>,
Mitchell Jones <mjones@21cenlogic.com> wrote:

In article <d1f3e5$slg$1@mail.specsol.com>,


wrote:

Mitchell Jones <mjones@21cenlogic.com> wrote:

<snip>

***{Meaning, I suppose, that some of the water flashes to steam at the
bottom, and spits the rest of the liquid out the top of the tube? And
the chip is there, I guess, to acquire the kinetic energy in place of
the liquid, and then give it back via frictional losses, thereby keeping
the liquid in the tube? I guess that makes sense. --MJ}***


No, it provides nucleation points which causes bubbles to form.


***{The bubbles, presumably, would be steam. Steam does not form due to
"nucleation points." It forms because that portion of the water received
its heat of vaporization. After a bubble forms, of course, the point in
question can be described as a "nucleation point," but that does not
mean nucleation is the *cause* of the formation of the bubble. It is, in
fact, just another way of saying a bubble formed. The cause is the fact
that the water at that location got the heat it needed to flash to
steam. That would be the water in contact with the wall of the test tube
adjacent to the point where the heat was applied.

Ever heat liquids in test tubes with and without boiling chips? It makes
a difference, and you can see where the bubbles form.
--
"You're not as dumb as you look. Or sound. Or our best testing
indicates." -- Monty Burns to Homer Simpson
.
User: "Mitchell Jones"

Title: Re: Urea 18 Mar 2005 05:11:44 PM
In article <d1fgtq$ur4$1@rainier.uits.indiana.edu>,
(Gregory L. Hansen) wrote:

In article <mjones-E4635D.14125618032005@spectator.sj.sys.us.xo.net>,
Mitchell Jones <mjones@21cenlogic.com> wrote:

In article <d1f3e5$slg$1@mail.specsol.com>,


wrote:

Mitchell Jones <mjones@21cenlogic.com> wrote:

<snip>

***{Meaning, I suppose, that some of the water flashes to steam at the
bottom, and spits the rest of the liquid out the top of the tube? And
the chip is there, I guess, to acquire the kinetic energy in place of
the liquid, and then give it back via frictional losses, thereby keeping
the liquid in the tube? I guess that makes sense. --MJ}***


No, it provides nucleation points which causes bubbles to form.


***{The bubbles, presumably, would be steam. Steam does not form due to
"nucleation points." It forms because that portion of the water received
its heat of vaporization. After a bubble forms, of course, the point in
question can be described as a "nucleation point," but that does not
mean nucleation is the *cause* of the formation of the bubble. It is, in
fact, just another way of saying a bubble formed. The cause is the fact
that the water at that location got the heat it needed to flash to
steam. That would be the water in contact with the wall of the test tube
adjacent to the point where the heat was applied.


Ever heat liquids in test tubes with and without boiling chips? It makes
a difference, and you can see where the bubbles form.

***{I've not spent much time playing with test tubes. I have, however,
observed where the bubbles form when water boils, both in teakettles and
water heaters: they form where the heat is being applied. I assume they
do the same thing in a test tube. As for the situation when a boiling
chip is present, it becomes a question of whether the chip reaches the
boiling point before the glass. If the chip is opaque and the glass is
transparent, it could very well do that. In that case, the water would
flash to steam first on the surface of the boiling chip. If that
happened, however, it would have nothing to do with any sort of
"vaporization nuclei" being involved. The volume element would flash to
steam because the water within it had received its required heat of
vaporization, and for no other reason. --MJ}***
.
User: ""

Title: Re: Urea 18 Mar 2005 05:44:30 PM
Mitchell Jones <mjones@21cenlogic.com> wrote:

In article <d1fgtq$ur4$1@rainier.uits.indiana.edu>,
glhansen@steel.ucs.indiana.edu (Gregory L. Hansen) wrote:

<snip>

Ever heat liquids in test tubes with and without boiling chips? It makes
a difference, and you can see where the bubbles form.

***{I've not spent much time playing with test tubes. I have, however,
observed where the bubbles form when water boils, both in teakettles and
water heaters: they form where the heat is being applied. I assume they
do the same thing in a test tube. As for the situation when a boiling
chip is present, it becomes a question of whether the chip reaches the
boiling point before the glass. If the chip is opaque and the glass is
transparent, it could very well do that. In that case, the water would
flash to steam first on the surface of the boiling chip. If that
happened, however, it would have nothing to do with any sort of
"vaporization nuclei" being involved. The volume element would flash to
steam because the water within it had received its required heat of
vaporization, and for no other reason. --MJ}***

Yet more babble.
A general discussion of the phenomena:
http://www.monashscientific.com.au/Bumping.htm
Freezing and boiling; boiling chips discussed at the bottom:
http://chemed.chem.purdue.edu/genchem/topicreview/bp/ch14/melting.html
More about boiling and boiling chips:
http://www.heartmagic.com/zzBoilingPoints.html
--
Jim Pennino
Remove -spam-sux to reply.
.



User: ""

Title: Re: Urea 18 Mar 2005 03:14:13 PM
Mitchell Jones <mjones@21cenlogic.com> wrote:

In article <d1f3e5$slg$1@mail.specsol.com>,


wrote:

Mitchell Jones <mjones@21cenlogic.com> wrote:

<snip>

***{Meaning, I suppose, that some of the water flashes to steam at the
bottom, and spits the rest of the liquid out the top of the tube? And
the chip is there, I guess, to acquire the kinetic energy in place of
the liquid, and then give it back via frictional losses, thereby keeping
the liquid in the tube? I guess that makes sense. --MJ}***


No, it provides nucleation points which causes bubbles to form.

***{The bubbles, presumably, would be steam. Steam does not form due to
"nucleation points." It forms because that portion of the water received
its heat of vaporization. After a bubble forms, of course, the point in
question can be described as a "nucleation point," but that does not
mean nucleation is the *cause* of the formation of the bubble. It is, in
fact, just another way of saying a bubble formed. The cause is the fact
that the water at that location got the heat it needed to flash to
steam. That would be the water in contact with the wall of the test tube
adjacent to the point where the heat was applied. The advantage of
applying the heat from the side would be that if a volume element
flashed to steam at that location, it would mainly thrust the liquid in
the tube horizontally, toward the opposite wall, rather than vertically,
and out of the test tube. --MJ}***

Pure babble.
It is the sharp points that get the bubbles started, nothing more,
nothing less.

It is the same physics that causes a clean cup of water heated in a
microwave to boil over when you dump the instant coffee in it.

***{Instant coffee contains lots of volatile oils that vaporize at
temperatures well below the boiling point of water. The foaming that you
see occurs despite the fact that none of the water is flashing to steam.
Each point where a bubble appears, of course, is a "nucleation point,"
because that's just another way of saying a bubble appeared there. But,
again, it is the fact that enough heat was delivered to vaporize the
oil, which is the cause of the bubble formation at that location. There
are, of course, "condensation nuclei"--i.e., particles which facilitate
condensation--but a parallel notion of "vaporization nuclei" would be a
stretch under the best circumstances, and it certainly does not apply to
the situation we are discussing. --MJ}***

Yet more babble.
Substitue dried sand, diamond dust, or anything else you like with sharp
points for the coffee and you get the same result.
Google "superheated water", 11,900 hits.
--
Jim Pennino
Remove -spam-sux to reply.
.
User: "Mitchell Jones"

Title: Re: Urea 18 Mar 2005 05:27:56 PM
In article <d1fgb5$71s$1@mail.specsol.com>,

wrote:

Mitchell Jones <mjones@21cenlogic.com> wrote:

In article <d1f3e5$slg$1@mail.specsol.com>,


wrote:


Mitchell Jones <mjones@21cenlogic.com> wrote:

<snip>

***{Meaning, I suppose, that some of the water flashes to steam at the
bottom, and spits the rest of the liquid out the top of the tube? And
the chip is there, I guess, to acquire the kinetic energy in place of
the liquid, and then give it back via frictional losses, thereby
keeping
the liquid in the tube? I guess that makes sense. --MJ}***


No, it provides nucleation points which causes bubbles to form.


***{The bubbles, presumably, would be steam. Steam does not form due to
"nucleation points." It forms because that portion of the water received
its heat of vaporization. After a bubble forms, of course, the point in
question can be described as a "nucleation point," but that does not
mean nucleation is the *cause* of the formation of the bubble. It is, in
fact, just another way of saying a bubble formed. The cause is the fact
that the water at that location got the heat it needed to flash to
steam. That would be the water in contact with the wall of the test tube
adjacent to the point where the heat was applied. The advantage of
applying the heat from the side would be that if a volume element
flashed to steam at that location, it would mainly thrust the liquid in
the tube horizontally, toward the opposite wall, rather than vertically,
and out of the test tube. --MJ}***


Pure babble.

It is the sharp points that get the bubbles started, nothing more,
nothing less.

***{Horse manure. I heated a cup of water to a boil on my stove and
dumped sand in it. Nothing happened. --MJ}***

It is the same physics that causes a clean cup of water heated in a
microwave to boil over when you dump the instant coffee in it.


***{Instant coffee contains lots of volatile oils that vaporize at
temperatures well below the boiling point of water. The foaming that you
see occurs despite the fact that none of the water is flashing to steam.
Each point where a bubble appears, of course, is a "nucleation point,"
because that's just another way of saying a bubble appeared there. But,
again, it is the fact that enough heat was delivered to vaporize the
oil, which is the cause of the bubble formation at that location. There
are, of course, "condensation nuclei"--i.e., particles which facilitate
condensation--but a parallel notion of "vaporization nuclei" would be a
stretch under the best circumstances, and it certainly does not apply to
the situation we are discussing. --MJ}***


Yet more babble.

Substitue dried sand, diamond dust, or anything else you like with sharp
points for the coffee and you get the same result.

***{More horse manure. I tried it, and it didn't work. --MJ}***

Google "superheated water", 11,900 hits.

***{Google a new brain. You said "heated," not "superheated." I know the
difference, even if you apparently do not. Now go away and stop wasting
my time. --MJ}***
.
User: ""

Title: Re: Urea 18 Mar 2005 05:59:43 PM
Mitchell Jones <mjones@21cenlogic.com> wrote:

In article <d1fgb5$71s$1@mail.specsol.com>,


wrote:

<snip>

Pure babble.

It is the sharp points that get the bubbles started, nothing more,
nothing less.

***{Horse manure. I heated a cup of water to a boil on my stove and
dumped sand in it. Nothing happened. --MJ}***

Of course not.
To see the effect you have to use a clean, smooth container such as a
test tube or beaker, use clean water, and heat it to just below the
apparent boiling point.
It is more dramatic if you boil the water first to drive off gases, let
it cool, then bring it to just below the apparent boiling point.
It is also more dramatic if you use a microwave oven which heats the
water but only heats the container by conduction from the water.
<snip>

Substitue dried sand, diamond dust, or anything else you like with sharp
points for the coffee and you get the same result.

***{More horse manure. I tried it, and it didn't work. --MJ}***

Then you don't know what you're doing since it works for everyone else.

Google "superheated water", 11,900 hits.

***{Google a new brain. You said "heated," not "superheated." I know the
difference, even if you apparently do not. Now go away and stop wasting
my time. --MJ}***

If you had bothered to look up a few articles, you would have discovered
that local superheating within the volume of liquid is what causes the
eruption to occur when you don't have something to provide nucleation
points.
All this is well documented and a few minutes of reading would erase
your ignorance.
--
Jim Pennino
Remove -spam-sux to reply.
.
User: "Mitchell Jones"

Title: Re: Urea 18 Mar 2005 07:22:46 PM
In article <d1fq1f$7ag$1@mail.specsol.com>,

wrote:

Mitchell Jones <mjones@21cenlogic.com> wrote:

In article <d1fgb5$71s$1@mail.specsol.com>,


wrote:


<snip>

Pure babble.

It is the sharp points that get the bubbles started, nothing more,
nothing less.


***{Horse manure. I heated a cup of water to a boil on my stove and
dumped sand in it. Nothing happened. --MJ}***


Of course not.

To see the effect you have to use a clean, smooth container such as a
test tube or beaker, use clean water, and heat it to just below the
apparent boiling point.

It is more dramatic if you boil the water first to drive off gases, let
it cool, then bring it to just below the apparent boiling point.

***{Irrelevant. The subject under discussion was quite specific, and
that was not it. The original poster did not claim to have done any such
thing, and it is not reasonable to suppose that, as a child playing
around by boiling pee in a test tube, he would have done so. --MJ}***

It is also more dramatic if you use a microwave oven which heats the
water but only heats the container by conduction from the water.

***{Irrelevant. The experiment described by the original poster took
place 40 years ago, before microwave ovens were publicly available. He
said he held an 8-inch test tube with a clothes peg, and heated it with
a candle. Here are his exact words:
"IIRC, (40 years ago) we used a 1 inch x 8 inch test tube and a candle
under the bottom, held it with a clothes peg. It would boil up 2-3
times then boom, splat, I felt a noticable recoil. A few years later a
China man who lived there as a kid in the 30's explained how he and his
friends would use a spoon to scrape off deposits from urinals and
toilets to make fireworks."
--Mitchell Jones}***

<snip>

Substitue dried sand, diamond dust, or anything else you like with sharp
points for the coffee and you get the same result.


***{More horse manure. I tried it, and it didn't work. --MJ}***


Then you don't know what you're doing since it works for everyone else.

Google "superheated water", 11,900 hits.


***{Google a new brain. You said "heated," not "superheated." I know the
difference, even if you apparently do not. Now go away and stop wasting
my time. --MJ}***


If you had bothered to look up a few articles, you would have discovered
that local superheating within the volume of liquid is what causes the
eruption to occur when you don't have something to provide nucleation
points.

All this is well documented and a few minutes of reading would erase
your ignorance.

***{Yup, my comments are "babbling," and I'm ignorant as a post,
according to you! There is no possibility whatever that there might be
an exothermic reaction going on in the situation the fellow described,
or so you say. And the stuff about the "China man" who lived there in
the 30's, who scraped deposits off of urinals and made fireworks, why
that must have been a flat-out lie! Why, its all "local superheating
within the volume of liquid,"--with a goddamned candle, for Christ's
sake! And you know that to be a fact because you are obviously Zeus
himself, down from Mt. Olympus to clue us all in! --MJ}***
.
User: "tj Frazir"

Title: Re: Urea 18 Mar 2005 07:51:37 PM
Idiot . adding surgar orsalt will lower the boiling point as it melts .

.

User: ""

Title: Re: Urea 18 Mar 2005 07:30:45 PM
Mitchell Jones <mjones@21cenlogic.com> wrote:

In article <d1fq1f$7ag$1@mail.specsol.com>,


wrote:

Mitchell Jones <mjones@21cenlogic.com> wrote:

In article <d1fgb5$71s$1@mail.specsol.com>,


wrote:


<snip>

Pure babble.

It is the sharp points that get the bubbles started, nothing more,
nothing less.


***{Horse manure. I heated a cup of water to a boil on my stove and
dumped sand in it. Nothing happened. --MJ}***


Of course not.

To see the effect you have to use a clean, smooth container such as a
test tube or beaker, use clean water, and heat it to just below the
apparent boiling point.

It is more dramatic if you boil the water first to drive off gases, let
it cool, then bring it to just below the apparent boiling point.

***{Irrelevant. The subject under discussion was quite specific, and
that was not it. The original poster did not claim to have done any such
thing, and it is not reasonable to suppose that, as a child playing
around by boiling pee in a test tube, he would have done so. --MJ}***

It is also more dramatic if you use a microwave oven which heats the
water but only heats the container by conduction from the water.

***{Irrelevant. The experiment described by the original poster took
place 40 years ago, before microwave ovens were publicly available. He
said he held an 8-inch test tube with a clothes peg, and heated it with
a candle. Here are his exact words:
"IIRC, (40 years ago) we used a 1 inch x 8 inch test tube and a candle
under the bottom, held it with a clothes peg. It would boil up 2-3
times then boom, splat, I felt a noticable recoil. A few years later a
China man who lived there as a kid in the 30's explained how he and his
friends would use a spoon to scrape off deposits from urinals and
toilets to make fireworks."
--Mitchell Jones}***

<snip>

Substitue dried sand, diamond dust, or anything else you like with sharp
points for the coffee and you get the same result.


***{More horse manure. I tried it, and it didn't work. --MJ}***


Then you don't know what you're doing since it works for everyone else.

Google "superheated water", 11,900 hits.


***{Google a new brain. You said "heated," not "superheated." I know the
difference, even if you apparently do not. Now go away and stop wasting
my time. --MJ}***


If you had bothered to look up a few articles, you would have discovered
that local superheating within the volume of liquid is what causes the
eruption to occur when you don't have something to provide nucleation
points.

All this is well documented and a few minutes of reading would erase
your ignorance.

***{Yup, my comments are "babbling," and I'm ignorant as a post,
according to you! There is no possibility whatever that there might be
an exothermic reaction going on in the situation the fellow described,
or so you say. And the stuff about the "China man" who lived there in
the 30's, who scraped deposits off of urinals and made fireworks, why
that must have been a flat-out lie! Why, its all "local superheating
within the volume of liquid,"--with a goddamned candle, for Christ's
sake! And you know that to be a fact because you are obviously Zeus
himself, down from Mt. Olympus to clue us all in! --MJ}***

Ignorant twit, just about any liquid will erupt from a test tube if
you aren't careful or don't use a boiling chip.
Read the web references if you don't want to remain an ignorant twit.
*PLONK*
--
Jim Pennino
Remove -spam-sux to reply.
.













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